Combination effects of cation and anion of ionic liquids on the cadmium metal-organic frameworks in lonothermal systems

The effects of cation and/or anion of two groups of ionic liquids ([EMI]X and [PMI]X, where EMI = 1-ethyl-3-methylimidazolium; PMI = 1-propyl-3-methylimidazolium; X = Cl, Br, and 1) on the ionothermal reactions between Cd(NO3)(2).4H(2)O and 1,3,5-benzenetricarboxylic acid (H3BTC) were studied. Three different CdBTC metal-organic frameworks, [EMI][Cd-2(BTC)Cl-2)(1), [EMI[Cd(BTC)](2), and [PMI][Cd(BTC)1(3), were formed into crystalline phases. 1 was obtained from reactions in [EMI]Cl, while the same reactions with Cl replaced by Br or I produced a known compound 2. The replacement of EMI+ by PMI+ produced 3, irrespective of the nature of X.