期刊
INORGANIC CHEMISTRY
卷 47, 期 6, 页码 1907-1909出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic800071g
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资金
- National Research Foundation of Korea [2005-005-J11903] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The effects of cation and/or anion of two groups of ionic liquids ([EMI]X and [PMI]X, where EMI = 1-ethyl-3-methylimidazolium; PMI = 1-propyl-3-methylimidazolium; X = Cl, Br, and 1) on the ionothermal reactions between Cd(NO3)(2).4H(2)O and 1,3,5-benzenetricarboxylic acid (H3BTC) were studied. Three different CdBTC metal-organic frameworks, [EMI][Cd-2(BTC)Cl-2)(1), [EMI[Cd(BTC)](2), and [PMI][Cd(BTC)1(3), were formed into crystalline phases. 1 was obtained from reactions in [EMI]Cl, while the same reactions with Cl replaced by Br or I produced a known compound 2. The replacement of EMI+ by PMI+ produced 3, irrespective of the nature of X.
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