期刊
INORGANIC CHEMISTRY
卷 47, 期 21, 页码 9958-9964出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic801174d
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资金
- EPSRC [EP/C528816/1]
- Engineering and Physical Sciences Research Council [EP/C528816/1] Funding Source: researchfish
- Natural Environment Research Council [NE/C513169/1] Funding Source: researchfish
A series of silicon-centered connecting units, MenSi(p-C6H4CO2H)(4-n) (n = 0, 1, 2), have been prepared and their coordination polymers with Zn(II) metal atoms studied. The tetra-acid L1 (n = 0) acts as a tetrahedral node and reacts with Zn(II) centers to give 1, a novel interpenetrating 3D network containing distorted tetrahedral bimetallic secondary building units (SBUs). The triacid L2 (n = 1) acts as a trigonal pyramidal node and forms an intercalated 2D layered network, 2, with Zn(II) ions, containing distorted octahedral tetranuclear SBUs. Last, the bent diacid L3 (n = 2) reacts with Zn(II) centers to give 3, a corrugated 2D layered structure containing 1D zinc hydroxo chains. Together these three new coordination polymers demonstrate the potential versatility of tetravalent silicon containing connecting ligands for metal-organic framework construction.
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