期刊
INORGANIC CHEMISTRY
卷 47, 期 20, 页码 9137-9139出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic801366r
关键词
-
资金
- EPSRC
- University of Glasgow
The unsymmetrical Mn-Anderson polyoxometalate cluster, [N(C4H9)(4)](3)[MnMo6O18(C4H6O3NO2)(C4H6O3NH2)] (1; N(C4H9)(4)(+) = TBA(+)), has been prepared and characterized by X-ray crystallography and electrospray ionization mass spectrometry (ESI-MS). Covalent functionalization of compound 1 leads to the controlled assemblies of unsymmetrical alkoxopolyoxometalate clusters of compounds 2-5, which can be directly observed in solution as revealed by ESI-MS studies.
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