期刊
INORGANIC CHEMISTRY
卷 47, 期 18, 页码 7936-7938出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic800700h
关键词
-
资金
- U.S. Dept. of Energy, Office of Science [DE-FG020 1 ER 15244]
- Argonne National Laboratory (Laboratory-Grad Fellowship for KLM)
A 2-fold interwoven metal-organic framework has been chemically reduced and doped with Li+, Na+, and K+. At low pressures and temperatures, the reduced and doped materials exhibit enhanced H-2 uptake-up to 65% higher than for the neutral framework. Notably, at similar doping levels, H-2 binding is strongest with Li+ and decreases as Li+ > Na+ > K+. However, the uptake increases in the opposite order. We attribute the behavior to structural changes accompanying framework reduction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据