期刊
INORGANIC CHEMISTRY
卷 47, 期 18, 页码 8086-8090出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic800827a
关键词
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资金
- 973 Key Program [2006CB932904, 2007CB815304, 2007CB815300]
- National Natural Science Foundation of China [20425313, 20521101]
- Chinese Academy of Sciences [KJCX2-YW-MO5]
- Natural Science Foundation of Fujian Province [2006F3135]
A new optical supramolecular compound constructed from a polyoxometalate cluster and an organic substrate [(H3O)(C12H10N3)(2)(PW12O40)] (1) has been synthesized via a hydrothermal reaction and has been structurally characterized by X-ray diffraction. The solid-state diffuse reflectance, IR, and photoluminescence spectra of the title compound indicate that there is an interaction between the alpha-PW12O40 and the organic substrate. The light-yellow title compound shows a certain second-order nonlinear optical response of I-2 omega = 2I(KDP)(2 omega).
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