期刊
INORGANIC CHEMISTRY
卷 47, 期 22, 页码 10190-10192出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic801282r
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资金
- DGESIC [CTQ2005-08989-C01-C02/13QU]
- MEC for Consolider Ingenio 2010 [CSD2006-0003]
- ICIQ Foundation
- DURSI [2005SGR00108]
- ICREA Funding Source: Custom
The combination of the square-planar cis-protected [Pt(dppp) (O3SCF3)(2)] (M) with the ditopic N, N'-bis(3,5-dimethyl-4-pyridinyl)-4-ethoxy-2,6-pyridinedicarboxamide ligand (L) leads both in solution and in the solid state to the quantitative self-assembly of a M2L2 metallocycle. We also report crystallographic evidence derived from the solid-state structure of the dinuclear metallocycle in support of the existence of anion-pi-pi interactions.
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