期刊
INORGANIC CHEMISTRY
卷 47, 期 22, 页码 10223-10225出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic8018452
关键词
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资金
- U.S. Department of Energy's Office of Science [DE-FG02-01ER15244]
- Argonne National Laboratory
- Northwestern Nanoscale Science and Engineering Center
A robust, noncatenated, and permanently microporous metal-organic framework (MOF) material has been synthesized by combining a new nonplanar ligand, 4,4',4 '',4'''-benzene-1,2,4,5-tetrayltetrabenzoic acid, with a zinc(II) source under solvothermal conditions. The new material features cavities that are readily modified via activation and functionalization of framework nodes (as opposed to struts). A preliminary investigation of the empty cavity version of the material and six cavity-modified versions reveals that modification can substantially modulate the MOF's internal surface area, pore volume, and ability to sorb molecular hydrogen.
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