期刊
INORGANIC CHEMISTRY
卷 47, 期 22, 页码 10187-10189出版社
AMER CHEMICAL SOC
DOI: 10.1021/ic8014332
关键词
-
资金
- NSF [CHE-0716304]
- ACS PRF [43048-AC3]
- Luce Foundation
An electron-rich nickel(I) beta-diketiminate cleaves the E-NO bond of O-, S-, and N-organonitrosci species to give the nickel nitrosyl [Me3NN]NiNO along with dimeric nickel(II) alkoxide or thiolate complexes {[Me3NN]Ni}(2)(mu-E)(2) or the mononuclear nickel(II) amide [Me3NN]NiNPh2. This diamagnetic three-coordinate amide exhibits temperature-dependent NMR spectra due to a low-lying triplet state.
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