期刊
INDUSTRIAL CROPS AND PRODUCTS
卷 124, 期 -, 页码 244-253出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.indcrop.2018.07.079
关键词
Rosin; Rosin derived acrylic monomer; Miniemulsion polymerization; Pressure-sensitive adhesive
资金
- Fundamental Research Funds for the Central Nonprofit Research Institution of CAF [CAFYBB2016ZD007]
- National Natural Science Foundation of China [31570579]
- National Key R&D Program of China [2017YFE0106800]
A series of rosin stabilized nanoparticles were prepared by miniemulsion polymerization. The hydrophobicity of dehydroabietic acid (DA) from rosin or from DA derived acrylic monomer (AEDA) was employed to stabilize the monomer miniemulsions. Then miniemulsion polymerizations of these monomer miniemulsions were performed separately and achieved the rosin stabilized nanoparticles with a near-monodisperse spherical morphology, respectively. This approach can effectively incorporate DA or AEDA into polyacrylate miniemulsinn. Herein, AEDA played a role as both costabilizer and reactant in miniemulsion polymerization, and high molecular weight AEDA-MMA copolymers were achieved. The introduction of rosin's moiety also could afford its copolymers with an improved thermal stability and mechanical property. Unlike conventional usage of rosin derivatives as a tackifying resin in pressure-sensitive adhesives (PSA), AEDA served as a hard component and improved the holding power of PSA, which opens a new platform for the using of rosin.
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