期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 53, 期 23, 页码 9754-9763出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie500986n
关键词
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资金
- National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [2012R1A1A4A01005951]
- National Research Foundation of Korea [2012R1A1A4A01005951] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
This work reports an electron beam irradiation (30 kGy and 90 kGy) approach to narrow the band gap of the pristine CeO2 nanostructure (p-CeO2) to enhance their visible light activity through defect engineering. This was confirmed by diffuse reflectance spectroscopy, photoluminescence, Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller, electrochemical impedance spectroscopy, and linear scan voltammetry. XPS revealed changes in the surface states, composition, Ce4+ to Ce3+ ratio, and other defects in the modified CeO2 nanostructures (m-CeO2). The m-CeO2 exhibits excellent photocatalytic activities by degrading 4-nitrophenol and methylene blue in the presence of visible light (lambda > 400 nm) compared to the p-CeO2. The optical, photocatalytic, and photoelectrochemical studies and proposed mechanism further support the enhanced visible light photocatalytic activities of the m-CeO2. This study confirmed that defect-induced band gap engineered m-CeO2 could be used effectively as photocatalyst and photoelectrodes owing to their enhanced visible light photocatalytic activities.
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