期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 53, 期 3, 页码 1033-1039出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie402633n
关键词
-
资金
- National Natural Science Foundation of China [20107005, 20977069]
- Jiangxi Provincial Department of Education [GJJ13557]
- Ph.D. Research Startup Foundation of Jiangxi Science and Technology Normal University [30009901 15]
The Fe2+-activated persulfate (PS) oxidation of toluene was evaluated using single-factor tests and response surface methodology (RSM). The results indicated the degradation efficiency increased as the PS and Fe2+ concentrations increased, while excessive dosages inhibited the degradation efficiency. The pH had an insignificant effect on the degradation of toluene. Based on the RSM optimization approach, the degradation efficiency reached a maximum of 84.4%. The main intermediates were also separated and identified by GC MS, and a plausible degradation pathway of toluene was proposed. Further studies of surfactant recovery from flushing effluents mixed with toluene and surfactant were explored. Compared with the Fe2+/H2O2 process, a great enhancement of the toluene degradation efficiency and lower sodium dodecyl sulfate (SDS) degradation efficiency were obtained by the Fe2+/PS process. The results demonstrated that the Fe2+/PS selective oxidation process could be used for SDS recovery and for the degradation of contaminants present in soil flushing effluents.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据