4.6 Article

Novel Ionic Liquid Supported on a Magnetic Core and Its Catalytic Activities

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 53, 期 44, 页码 17325-17332

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AMER CHEMICAL SOC
DOI: 10.1021/ie502681w

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  1. National Natural Science Foundation of China [21103111]

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An acidic ionic liquid immobilized on a magnetic core has been synthesized through the copolymerization of acidic vinylpyridinium IL with a double-bond-modified magnetic core. The ionic liquid was coated on the magnetic core to form a shell structure that provided easily accessible acidic sites for reactants. The magnetic attraction between the particles enhanced the interactions of the ions on the shell surface, resulting in a high stability. The solid acid exhibited a high activity for biodiesel synthesis from waste oils, with a yield of 99% under mild conditions. The simple magnetic recovery of the prepared catalyst adds to its advantages over other acid catalysts.

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