4.6 Article

Bacteria Cellulose Nanofibers Supported Palladium(0) Nanocomposite and Its Catalysis Evaluation in Heck Reaction

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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 51, 期 16, 页码 5743-5748

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AMER CHEMICAL SOC
DOI: 10.1021/ie300395q

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资金

  1. National Natural Science Foundation of China [21074055]
  2. Research Fund for the Doctoral Program of Higher Education of China [20113219110037, 20103219120008]

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Bacteria cellulose (BC) nanofibers supported palladium(0) nanocomposites were prepared and fully characterized in terms of morphology, crystallinity, composition, and thermal stability. The as-prepared catalyst was further successfully explored in Heck coupling reaction between aryl halide and styrene or acrylates, with a yield over 86-96% for the first coupling reaction. With coupling yields decreased less than 10% for the fifth reaction cycle, Pd/BC catalyst exhibits great potential as recyclable catalyst for Heck coupling.

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