期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 51, 期 15, 页码 5433-5437出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie202628m
关键词
-
资金
- Shanghai Leading Academic Discipline Project [J51503]
- National Natural Science Foundation of China [20976105]
- Science and Technology Commission of Shanghai Municipality [09QT1400600]
- Shanghai Municipal Education Commission [11ZZ179, 09YZ387]
The catalytic synthesis from transesterification of dimethyl carbonate (DMC). and 1-pentanol (1-PeOH) over alkaline ionic liquid 1-butyl-3-methylimidazolium hydroxide ([bmIm]OH), as well as the optimal reaction conditions, was studied. Results showed that [bmIm]OH exhibited high activity and when the reaction time was 4 h, catalyst dosage was 2.0%, n(DMC):n(1-PeOH) was 1:4, and the dipentyl carbonate (DPC) yield was up to 75.81%. After the alkaline ionic liquid [bmIm]OH was used 5 times repeatedly, the catalytic activity still remained at 94%.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据