4.6 Article

Byproduct Hydrogen Network Design Using Pressure Swing Adsorption and Recycling Unit for the Petrochemical Complex

期刊

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 50, 期 6, 页码 3304-3311

出版社

AMER CHEMICAL SOC
DOI: 10.1021/ie100683c

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资金

  1. Korea Science and Engineering Foundation provided through the Advanced Environmental Biotechnology Research Center [R11-2003-006]
  2. MKE [10031883]
  3. Ministry of Land, Transportation and Maritime Affairs (MLTM) of the Korean government
  4. Korea Agency for Infrastructure Technology Advancement (KAIA) [50047] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  5. Korea Evaluation Institute of Industrial Technology (KEIT) [2005B02901] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  6. National Research Foundation of Korea [2003-0037636] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Hydrogen, which has gained attention as the next-generation renewable energy source among byproducts, is a raw material that is commonly produced and consumed in all petrochemical complexes. It is also a primary energy source in energy systems that can considerably reduce air pollution and greenhouse gas emission. Therefore, an explosive demand for hydrogen is expected in the future. A considerable amount of hydrogen is produced as byproducts in industrial complexes such as petrochemical plants and oil refineries within a petrochemical complex; however, this hydrogen is mostly used as fuel internally. If a considerable amount of hydrogen that is used as fuel can be recycled as raw material for an energy source or for other processes, hydrogen can be of a considerably higher value than it is at present. In this research, we have designed a byproduct hydrogen network between a sour:e and a sink within a petrochemical complex. We determined the minimum fresh hydrogen and recovery hydrogen that are needed for forming a material exchange network through hydrogen pinch analysis and finally designed the hydrogen recycling network between the source plant and the sink plant by building a network optimization problem in which the cost and constraints needed to build the network were considered.

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