期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 49, 期 15, 页码 6909-6915出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie901785j
关键词
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资金
- Comision de Investigaciones Cientificas de la Provincia de Buenos Aires (CICPBA)
- Universidad de General San Martin [5A08/011]
- Agencia Nacional de la Promocion de la Ciencia y la Tecnologia (ANPCyT) [PAE 22257]
The applicability of different photochemical advanced oxidation technologies (PAOTs), namely, direct UV-C photolysis, UV-C/H2O2 and UV-A/TiO2 heterogeneous photocatalysis (HP), and photo-Fenton reactions (UV-A/H2O2/Fe2+, PF), for the degradation of 300 mg LT-1 nonylphenol ethoxylate-9 (NPE-9) in water is described. Different kinetic regimes for each PAOT were found, and as a result, comparative efficiencies could be obtained only from final parameters such as NPE-9 conversion, TOC decrease, and aldehyde production after 3 h of treatment. The initial photonic efficiencies indicate, however, that UV-A processes make better use of photons than UV-C processes. Preliminary optimization of PF systems showed that the most efficient NPE-9/H2O2/Fe2+ molar ratio was 1:1:0.5. Degradation products were partially investigated. Fortunately, toxic 4-nonylphenol was never found as a byproduct of the degradation after any of the treatments. Aldehydes were formed in all of the processes, but they appeared at a low extent in PF reactions. Therefore, PF treatments were considered to be the best degradation processes.
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