期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 48, 期 23, 页码 10439-10447出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie900119z
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An experimental study was performed with an aged Co/Pt/Al2O3 catalyst in a laboratory slurry reactor to develop a macrokinetic expression for the Fischer-Tropsch (FT) synthesis. A semiempirical model was found to be the preferred two-parameter rate equation of the reaction. However, it was shown that this model is virtually indistinguishable from a mechanistically derived three-parameter rate model that assumes the following kinetically relevant steps in the cobalt-FT synthesis: CO dissociation occurs without hydrogen interaction and is not a rate-limiting step; the first hydrogen addition to surface carbon and the second hydrogen addition to surface oxygen are the rate-determining steps.
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