期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 48, 期 13, 页码 6291-6295出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie801979w
关键词
-
Two new precursor materials, (Mg(0.63)Zn(0.37))(Mn(0.1)Fe(1.8))O(3.85) (hereafter Mg-Zn) and (Mn(0.55)Zn(0.35)Fe(0).(1))Fe(2)O(4) (hereafter Mn-Zn), derived from the microelectronic ferrite materials studied earlier by us, were found to be catalytically active in primary alcohols transformation. Both Mg-Zn and Mn-Zn ferrites reveal dehydrogenating features, transforming a primary alcohol into an aldehyde, but they differ with respect to subsequent bimolecular condensation to symmetric ketone. The difference in selectivity can be tentatively explained by the different dispersion of surface both Lewis acidic centers and reducing centers as well as the presence of it strong synergic effect between these centers. The materials were tested by XRD, TPR, IR, and BET methods.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据