期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 47, 期 19, 页码 7131-7140出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie800455f
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A comprehensive study of the acid hydrolysis of the softwood species, Loblolly pine (Pinus taeda), using different hydrolysis conditions is presented. The effect of the type of acid, pH, reaction temperature, and reaction time on hydrolysis products such as monosaccharides (mannose, glucose, galactose, xylose, and arabinose) and the subsequent degradation products, 5-hydroxymethyl-2-furaldehyde (HMF) and 2-furaldehyde (furfural) is reported using a batch reactor. Trifluoroacetic acid (TFA) is found to yield the highest amount of overall soluble monosaccharides (similar to 70% yield from the hemicelluloses fraction) at 150 degrees C at pH 1.65. The mineral acids (HCl, H2SO4, HNO3, and H3PO4) gave a slightly lower yield of monosaccharides from hydrolyzed hemicellulose (similar to 60%). At 200 degrees C, cellulose is hydrolyzed by the mineral acids as evidenced by higher levels of solid dissolution and higher soluble hexose (relative to pentose) yields. Larger amounts of degradation products are also noted at higher temperatures. Furthermore, an increased amount of HMF and furfural is noted in the liquid product as compared to lower temperatures. TFA was found to be the most gentle acid, leading to limited monosaccharide degradation among the acids used. The presence of soluble oligosaccharides in solution after hydrolysis was confirmed by applying a secondary acid hydrolysis to the solid-free liquid hydrolysate. Good closure of mass balances was possible using total organic carbon (TOC) analysis.
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