期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 47, 期 3, 页码 539-545出版社
AMER CHEMICAL SOC
DOI: 10.1021/ie070552r
关键词
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Liquids that consist of a mixture of an alcohol and either an amidine or a guanidine have been developed to switch from a low-polarity form to a high-polarity ionic liquid upon treatment with CO2 at atmospheric pressure. Treatment with N-2 and/or mild heat (50-60 degrees C) reverses the process. These liquids can be used as switchable solvents to dissolve and then precipitate a solute or to dissolve reagents for a chemical synthesis and then precipitate the product.
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