MRI-compatible Nb-60Ta-2Zr alloy for vascular stents.: Electrochemical corrosion behavior in simulated plasma solution

Using revised simulated body fluid (r-SBF), the electrochemical corrosion behavior of an Nb-60Ta-2Zr alloy for MRI compatible vascular stents was characterized in vitro. As indicated by XPS analysis, the surface passive oxide film of approximately 1.3 nm thickness was identified as a mixture of Nb2O5, Ta2O5 and ZrO2 after immersion in the r-SBF. The Nb-60Ta-2Zr alloy manifests a low corrosion rate and high polarization resistance similar to pure Nb and Ta, as shown by the potentiodynamic polarization curves and EIS. Unlike 316L stainless steel and the L605 Co-Cr alloy, no localized corrosion has been detected. Semiconducting property of passive film on the Nb-60Ta-2Zr alloy was identified as the n-type, with growth mechanism of high-field controlled growth. The excellent corrosion resistance in simulated human blood enviroment renders the Nb-60Ta-2Zr alloy promising as stent candidate material. (C) 2015 Elsevier B.V. All rights reserved.