期刊
IEEE TRANSACTIONS ON NANOTECHNOLOGY
卷 7, 期 3, 页码 371-375出版社
IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
DOI: 10.1109/TNANO.2008.917781
关键词
Electrochemical processes; heterojunctions; impedance; interface phenomena; nanotechnology
类别
资金
- La Direccion General de Asuntos del Personal Academico-Universidad Nacional Autonoma de Mexico (DGAPA-UNAM) [IN-118406]
An electrostatic model is presented to explain the closed packing observed in anodic production of nanotubes. The model is suggested by the experimental results of impedance spectroscopy performed during the growth of titanium oxide nanotubes in a polar nonaqueous electrolyte. The dynamics of the process is represented with the capacitance and the dc current. Accordingly, a combination of electrostatic and chemical activity defines the structure formation, ranging from of porous random materials to self-structured materials. In this model, the geometry of the nanostructure can be controlled with the voltage.
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