期刊
MATERIALS CHARACTERIZATION
卷 107, 期 -, 页码 1-6出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2015.06.034
关键词
Barium titanate; Transmission electron microscopy; Lattice defects; Ferromagnetism
类别
资金
- National Natural Science Foundation of China [61474045]
- State Key Basic Research Program of China [2013CB922300]
Single-crystal and polycrystal BaTiO3 (BTO) materials synthesized by the physical and chemical methods, respectively, have been studied based on microstructural characterizations and magnetic measurements. The results of X-ray diffraction and Raman scatting spectra show that a single crystal tetragonal to polycrystalline pseudo-cubic structure transformation occurs in BTO ferroelectrics, dependent of growth conditions and interface effects. High-resolution transmission electron microscope data indicate that the as-prepared BTO/SrTiO3 (001) and BTO/SrRuO3/SrTiO3 (001) heterostructures are highly c-axis oriented with atomic sharp interfaces. Lattice defects (i.e., edge-type misfit dislocations and stacking faults) in the heterostructures could be identified clearly and showed tunable with the variations of interface strain. Furthermore, the effects of vacancy defects on magnetic properties of BTO are discussed, which shows a diamagnetism-ferromagnetism switching as intrinsic vacancies increase. This work opens up a possible avenue to prepare magnetic BTO ferroelectrics. (C) 2015 Elsevier Inc. All rights reserved.
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