期刊
MACROMOLECULAR MATERIALS AND ENGINEERING
卷 300, 期 11, 页码 1096-1107出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.201500126
关键词
copolyimide fibers; draw ratio; mechanical properties; molecular orientation
资金
- National Natural Science Foundation of China (NSFC) [51373008]
- Higher School Specialized Research Fund for Doctoral Priority Areas of Development Project [20130010130001]
- Fundamental Research Funds for the Central Universities of China [ZY 1408]
High performance fibers based on copolyimide (co-PI) containing benzimidazole and ether moieties were prepared via a two-step wet spinning method. The effects of draw ratio on the structures and properties of the fibers are investigated. The mechanical properties of the co-PI fibers are improved greatly by increasing draw ratio at temperatures above 400 degrees C, reaching the optimum tensile strength of 2.8GPa and modulus of 136GPa, which is due to the development of the molecular orientation along the fiber direction. The hot drawing process roughens the fiber surface and stretches the molecules in the fibers. Moreover, the fiber structure evolutions during the drawing process were also discussed and a smectic A liquid crystal-like model was proposed.
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