Seasonal variations of temperature, acetylene and ethane in Saturn's atmosphere from 2005 to 2010, as observed by Cassini-CIRS

Acetylene (C2H2) and ethane (C2H6) are by-products of complex photochemistry in the stratosphere of Saturn. Both hydrocarbons are important to the thermal balance of Saturn's stratosphere and serve as tracers of vertical motion in the lower stratosphere. Earlier studies of Saturn's hydrocarbons using Cassini-CIRS observations have provided only a snapshot of their behaviour. Following the vernal equinox in August 2009, Saturn's northern and southern hemispheres have entered spring and autumn, respectively, however the response of Saturn's hydrocarbons to this seasonal shift remains to be determined. In this paper, we investigate how the thermal structure and concentrations of acetylene and ethane have evolved with the changing season on Saturn. We retrieve the vertical temperature profiles and acetylene and ethane volume mixing ratios from Delta(nu) over tilde = 15.5 cm(-1) Cassini-CIRS observations. In comparing 2005 (solar longitude, L-s similar to 308 degrees), 2009 (L-s similar to 3 degrees) and 2010 (L-s similar to 15 degrees) results, we observe the disappearance of Saturn's warm southern polar hood with cooling of up to 17.1 K +/- 0.8 K at 1.1 mbar at high-southern latitudes. Comparison of the derived temperature trend in this region with a radiative climate model (Section 4 of Fletcher et al., 2010 and Greathouse et al. (2013, in preparation)) indicates that this cooling is radiative although dynamical changes in this region cannot be ruled out. We observe a 21 +/- 12% enrichment of acetylene and a 29 +/- 11% enrichment of ethane at 25 degrees N from 2005 to 2009, suggesting downwelling at this latitude. At 15 S, both acetylene and ethane exhibit a decrease in concentration of 6 +/- 11% and 17 +/- 9% from 2005 to 2010, respectively, which suggests upwelling at this latitude (though a statistically significant change is only exhibited by ethane). These implied vertical motions at 15 degrees S and 25 degrees N are consistent with a recently-developed global circulation model of Saturn's tropopause and stratosphere(Friedson and Moses, 2012), which predicts this pattern of upwelling and downwelling as a result of a seasonally-reversing Hadley circulation. Ethane exhibits a general enrichment at mid-northern latitudes from 2005 to 2009. As the northern hemisphere approaches summer solstice in 2017, this feature might indicate an onset of a meridional enrichment of ethane, as has been observed in the southern hemisphere during/after southern summer solstice. (C) 2013 Elsevier Inc. All rights reserved.