Recovery of Th(IV) from acid leaching solutions of bastnaesite at low concentrations

Low concentrations of Th4+ were recovered using the hydrolysis products of poly(styrene-co-maleic anhydride) (PSMA) to form an amorphous thorium(IV) macromolecular complex. The adsorption behavior and mechanism of the as-prepared PSMA toward Th4+ were investigated. At the optimum pH value and adsorption dosage, the adsorption percentage of Th4+ was 97.93%, and the maximum adsorption capacity of Th4+ was 360.14 mg g(-1) at 40 degrees C within 1.5 h. The adsorption isotherm data were consistent with the Langmuir model, which confirmed the monolayer coverage mechanism of Th4+ onto the PSMA surface. The kinetic data followed a pseudo-second-order model, which suggested a chemisorption process. Through variation of pH values, Th4+ was efficiently enriched and separated from a simulated acid leaching solution of bastnaesite containing La3+ or Mg2+, and these selectivity coefficients were above 10(3). Inorganic acid decomposes the Th-PSMA complex easily and the regenerated PSMA resin can be utilized repeatedly. (C) 2014 Elsevier B.V. All rights reserved.