Hydrological control of dissolved organic carbon dynamics in a forested headwater catchment, Kiryu Experimental Watershed, Japan

To evaluate the influence of hydrological processes on dissolved organic carbon (DOC) dynamics in a forested headwater catchment, DOC concentration was observed along the flow path from rainfall to stream water via throughfall, soil water, groundwater, and spring water for 4 years, and DOC flux through the catchment was calculated. The spatial and temporal variations in DOC concentration and flux were compared with physical hydrological observations and the mean residence time of water. In the upslope soil layer, DOC concentrations were not significantly correlated with water fluxes, suggesting that DOC concentrations were not strictly controlled by water fluxes. In the upslope perennial groundwater, DOC concentration was affected by the change in the amount of microbial degradation of DOC produced by changes in the mean residence time of water. In stream water, the temporal variation in DOC concentration was usually affected by changes in DOC concentration of the inflow component via vertical infiltration from above the perennial groundwater. During dry periods, however, the component from inflow via vertical infiltration was negligible and DOC in the upslope perennial groundwater became the major component of stream water DOC. The temporal variation in stream water DOC concentration during baseflow was affected by rainfall patterns over several preceding months. Therefore, records of rainfall over several preceding months are one of the most important factors for predicting changes in DOC concentration on a catchment scale. Copyright (c) 2007 John Wiley & Sons, Ltd.