期刊
HOLZFORSCHUNG
卷 68, 期 4, 页码 435-446出版社
WALTER DE GRUYTER GMBH
DOI: 10.1515/hf-2013-0023
关键词
bio-based composites; cellulose fibers; epoxy resin; kraft lignin; pyrogallol; unidirectional reinforced composites
资金
- Federal Ministry for Food, Agriculture and Consumer Protection through the Agency for Renewable Resources (FNR) [FKZ 22025808]
A low-molecular lignin fraction (L) was extracted for the preparation of bio-based epoxy resins. Various compositions with the green 1,3-glycerol diglycidyl ether (1) and the co-component pyrogallol (2) were tested. In a first series of experiments, thermosets consisting of 1 and L, were studied with respect to variable lignin contents between 20 and 50%. The best thermoset has a tensile strength of 37 MPa and a Young's modulus of 2.2 GPa at 40% lignin input. Secondly, lignin-free compositions of 1 and 2 were prepared. For a molar fraction of the functional groups (n(OH) n(Epoxy)(-1)) of 130%, the tensile strength could be enhanced to 93 MPa and the modulus reached 3.7 GPa. Finally, systems with all three components were examined. The best mechanical performance of the corresponding neat thermosets was reached at n(OH) n(Epoxy)(-1) of 130%. Tensile strength decreases slightly to 86 MPa and Young's modulus remains nearly unchanged at 3.2 GPa. Two resin compositions, L+ 1 and L+ 1+ 2, were tested for the preparation of unidirectional composites reinforced with man-made cellulosic fibers (50% by vol.). The bending strength was 208 MPa in combination with a bending modulus of 12.5 GPa.
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