期刊
LANGMUIR
卷 31, 期 50, 页码 13478-13487出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.5b03899
关键词
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资金
- National Natural Science Foundation of China [51373149, 51333004]
- Natural Science Foundation of Zhejiang Province [R14E030003]
- Key Technology Program of Guizhou Province [2013-6016]
Immobilized polymer fractions have been claimed to be of vital importance for sol-gel transitions generally observed in nanoparticle dispersions but remain a matter of debate regarding mechanism and difficulty for prediction. Here we investigate the immobilized layer structures of trifunctionality polyether polyol (PPG) near the surfaces of hydrophilic and hydrophobic fumed silica (FS) nanoparticles to reveal the role of surface chemistry on the molecular dynamics and sol-gel transitions of the dispersions. Using modulated differential scanning calorimetry, we measure the specific heat capacity during glass transition and the enthalpy during cold-crystallization. Comparing with hydrophobic FS that forms a fully immobilized (glassy) layer) we find that hydrophilic FS immobilizes more PPG, forming a partially immobilized outer layer being unable, to crystallize next to the inner glassy layer. By correlating the thickness of the glassy layer with half of the minimum spacing between nanoparticles, we directly evidence the percolation of this layer along the nearest neighbor nanoparticles responsible for the sol-gel transition. Using,effective volume fraction including the glassy layer, we successfully construct master curves of relative viscosity of both hydrophilic and hydrophobic FS dispersions, pointing to a common sol-gel transition mechanism mediated by the surface chemistry.
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