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The rate constant of diatomic molecule dissociation within the shock forced oscillator model (SFO model)

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HIGH TEMPERATURE
卷 52, 期 4, 页码 518-529

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MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0018151X14030274

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A numerical analytical investigation of the shock forced oscillator (SFO) model as applied to the diatomic molecule AB-structureless particle M system is continued. The SFO model is based on the quantum theory of strong perturbations and allows one to estimate probabilities W (i -> f) for the transitions from level i to level f of diatomic molecule AB. The numerical analysis was carried out by the example of the nitrogen molecule N-2, with anharmonic description of the internuclear interaction potential. The intermolecular interaction potentials in the N-2-N-2 system are numerically analyzed using the Morse potential, the classical Lennard-Jones potential, and the improved Lennard-Jones potential.

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