期刊
LANGMUIR
卷 31, 期 36, 页码 9790-9798出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.5b02607
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资金
- French National Research Agency by the NANOFLUIDYN project [ANR-13-BS10-0009]
- Investissement d'Avenir program, by the Laboratory of Excellence NEXT [ANR-10-LABX-0037]
- MIMETIS project [ANR-10-EQPX-38-01]
- Agence Nationale de la Recherche (ANR) [ANR-13-BS10-0009] Funding Source: Agence Nationale de la Recherche (ANR)
We investigate the shape and mechanical properties of liquid interfaces down to nanometer scale by atomic force microscopy (AFM) and scanning electron microscopy (SEM) combined with in situ micromanipulation techniques. In both cases, the interface is probed with a cylindrical nanofiber with radius R of the order of 25-100 nm. The effective spring constant of the nanomeniscus oscillated around its equilibrium position is determined by static and frequency-modulation (FM) AFM modes. In the case of an unbounded meniscus, we find that the effective spring constant k is proportional to the surface tension gamma of the liquid through k = (0.51 +/- 0.06)gamma, regardless of the excitation frequency from quasi-static up to 450 kHz. A model based on the equilibrium shape of the meniscus reproduces well the experimental data. Electron microscopy allowed to visualize the meniscus profile around the fiber with a lateral resolution of the order of 10 nm and confirmed its catenary shape. The influence of a lateral confinement of the interface is also investigated. We showed that the lateral extension L of the meniscus influences the effective spring constant following a logarithmic evolution k similar to 2 pi gamma/ln(L/R) deduced from the model. This comprehensive study of liquid interface properties over more than 4 orders of magnitude in meniscus size shows that advanced FM-AFM and SEM techniques are promising tools for the investigation of mechanical properties of liquids down to nanometer scale.
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