期刊
HIGH PERFORMANCE POLYMERS
卷 26, 期 2, 页码 205-211出版社
SAGE PUBLICATIONS LTD
DOI: 10.1177/0954008313507590
关键词
CNT; DC conductivity; UHMWPE; Electrical percolation threshold; impedance analysis; polymer nanocomposite
资金
- Scientific Research Support Fund, Ministry of Higher Education and Scientific Research, Amman, Jordan [Bas/2/05/2010]
Carbon nanotube (CNT)/ultrahigh-molecular weight polyethylene (UHMWPE) nanocomposite with an electrical percolation threshold of only 0.1 wt% was prepared by simple dry mixing followed by compression molding. The nanocomposite microstructure, direct current and alternating current (AC) electrical conductivities, conduction mechanisms, and dielectric properties in the 10(1)-10(5) Hz frequency range have been investigated. Due to the localization of the nanofiller at the surface of UHMWPE powder particles, a segregated microstructure within the polymer matrix was created. Nanocomposites filled with 0.125-0.5 wt% CNT were found to follow the typical universal dynamic response behavior, and the characteristic frequency was found to increase with the increase in CNT concentration. At CNT concentration >= 0.5 wt%, the AC conductivity was found to be frequency independent over the entire frequency range studied.
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