期刊
HIGH ENERGY CHEMISTRY
卷 45, 期 2, 页码 99-103出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0018143911020147
关键词
-
资金
- Russian Foundation for Basic Research [09-03-00877a, 02.74011.0143]
The features of nanoparticle formation by the radiation-chemical reduction of Cu(2+) ions in polyacrylic acid-polyethyleneimine complexes have been studied. It has been shown that the swollen film/aqueous alcohol medium interphase exchange of the reducing species and the specifics of X-ray energy transfer play an important role in the formation of metal particles in the subsurface layer of polymer matrixes. An analysis of EPR and X-ray diffraction data shows that an acetaldehyde admixture increases the Cu(2+) reduction rate of and enables the growth of nanoparticles.
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