期刊
HIGH ENERGY CHEMISTRY
卷 42, 期 3, 页码 170-204出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0018143908030028
关键词
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Using the methods of emission spectroscopy and computer simulation, the kinetics of excitation of vibrational distribution functions (VDFs) for the A(3)Sigma(+)(u) (V(A) = 0-13), B(3)Pi (g) (V(B) = 0-17), and C(3)Pi(u) (V(C) = 0-4) electronic states of the nitrogen molecule in nitrogen of dc glow-discharge and electrode or resonant-cavity MW discharge plasmas was studied. The VDFs in the states A(3)Sigma(+)(u) (v(A) = 0-13), B(3)Pi (g) (v(B) = 0-17), and C(3)Pi (u) (v(C) = 0-4) of the nitrogen molecule differ from the Boltzmann distribution. The main processes that generate these distributions were determined. It was shown that the pattern of the calculated VDFs depends on experimental conditions, level rate coefficients and, what is of particular importance, on the cross sections of elementary processes used in the model.
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