期刊
HETEROCYCLES
卷 85, 期 5, 页码 1017-1043出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/REV-12-729
关键词
[2+2+2] Cycloaddition; Pyridine; Pyridone; Rhodium; Thiopyranimine
资金
- MEXT, Japan [20675002]
- Grants-in-Aid for Scientific Research [20675002] Funding Source: KAKEN
The transition-metal-catalyzed [2+2+2] cycloaddition of alkynes with nitriles is a useful and atom-economical method for the synthesis of substituted pyridines. The use of isocyanates and isothiocyanates in place of nitriles affords substituted pyridones and thiopyranimines, respectively. This review comprehensively covers the [2+2+2] cycloaddition reactions catalyzed by rhodium complexes for the synthesis of substituted pyridines, pyridones, and thiopyranimines. Asymmetric variants of these rhodium-catalyzed [2+2+2] cycloaddition reactions are also described.
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