期刊
HETEROCYCLES
卷 81, 期 8, 页码 1791-1798出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-09-11828
关键词
Alkaloid; Asymmetric Catalyst; Proline; Mannich Reaction; Total Synthesis
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
Proline catalyzed Mannich-Michael reaction of 3-ethyl-3-buten-2-one with 9-tosyl-3,4-dihydro-beta-carboline proceeded in a highly stereoselective manner. The reaction was applied to formal syntheses of dihydrocorynantheine and isorhynchophylline.
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