期刊
HETEROCYCLES
卷 77, 期 1, 页码 157-161出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-08-S(F)6
关键词
Cortistatin; Natural Product; Hypervalent Iodine; Oxidative Dearomatization; Cyclization
资金
- National Institutes of Health [HL25848]
- Guthikonda family
The feasibility of a hypervalent iodine-mediated oxidative dearomatization/cyclization to produce the oxabicyclo[3.2.1]octene of cortistatin A has been demonstrated through a model study. An interesting tandem cyclization via a Ritter intermediate has been observed when a slightly different substrate was used.
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