期刊
HETEROCYCLES
卷 77, 期 1, 页码 249-253出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-08-S(F)58
关键词
Benzylic Quaternary Carbon Center; (1,3-Butadien-2-yl)methanol; Buta-2,3-dienylstannane; Enantioselective Synthesis; Sporochnol A
资金
- Japan Promotion of Science
Ti(IV)-promoted reaction of the chiral acetals derived from aromatic aldehydes with 1-(tri-n-butyl)stannyl-2,3-butadiene followed by removal of the chiral auxiliary gave aryl(1,3-butadien-2-yl)methanols with high enantiomeric purity (>90% ee). The synthetic utility of this method was demonstrated by the formal synthesis of (-)-sporochnol A, a terpene possessing a chiral benzylic quaternary carbon center.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据