期刊
HELVETICA CHIMICA ACTA
卷 95, 期 3, 页码 448-454出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.201100256
关键词
1H-1; 2; 3-Triazoles; 1-aryl-; Click chemistry'; Multicomponent reactions
资金
- Natural Science Foundation of China [30873153]
- Key Projects of Shanghai in Biomedicine [08431902700]
- Scientific Research Foundation of the State Education Ministry for the Returned Overseas Chinese Scholars
The synthesis of monosubstituted 1-aryl-1H-1,2,3-triazoles was achieved in a one-pot reaction from arylboronic acids and prop-2-ynoic acid or calcium acetylide (=calcium carbide), respectively, as a source of acetylene, with yields ranging from moderate to excellent (Scheme 1, Table 2). The reaction conditions were successfully applied to arylboronic acids, including analogs with various functionalities. Unexpectedly, the 1,2,3-triazole moiety promoted a regioselective hydrodebromination (Scheme 2).
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