Article
Chemistry, Physical
Zhipeng Zheng, Yao Luo, Hua Yang, Zao Yi, Jianguo Zhang, Qianjv Song, Wenxing Yang, Chao Liu, Xianwen Wu, Pinghui Wu
Summary: A novel and structurally simple multifunctional broadband absorber is presented, using the thermogenic phase change properties of vanadium dioxide material to flexibly adjust absorption intensity and achieve near-perfect absorption in an ultra-broadband range.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Zhipeng Zheng, Ying Zheng, Yao Luo, Zao Yi, Jianguo Zhang, Zhimin Liu, Wenxing Yang, Yang Yu, Xianwen Wu, Pinghui Wu
Summary: This study proposes a terahertz metamaterial absorber that combines metamaterial structures and a VO2 film. Flexible switching of absorption performance and an ultra-broadband perfect absorption with a bandwidth of 3.3 THz can be achieved through temperature adjustment. The study also highlights the wide thermal tuning range of spectral absorbance.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Fei Zhao, Jiangchuan Lin, Zhenhua Lei, Zao Yi, Feng Qin, Jianguo Zhang, Li Liu, Xianwen Wu, Wenxing Yang, Pinghui Wu
Summary: In this work, the performance of c-Si/ZnO heterojunction ultrathin-film solar cells is enhanced by an integrated structure of c-Si trapezoidal pyramids on the top and Al pyramids in the active layer. The top c-Si pyramid increases absorption of short wavelengths and the bottom Al pyramid improves overall optical absorption, resulting in a high absorption rate of 93.16%. The optimized current density and conversion efficiency of the solar cells are 41.94 mA cm(-2) and 18.97%, respectively. The solar cells show good absorption in a wide range of incident angles and the electric field intensity profile demonstrates excellent light-trapping performance.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Review
Chemistry, Physical
Gagandeep Kaur, Harsh Kumar, Meenu Singla
Summary: This article presents the extensive utilization and range of ionic liquids in various fields, based on available literature. It provides a systematic and concise analysis of the applications of different ionic liquids, highlighting recent significant advances in each area. This review contributes to enhancing the understanding of the substantial knowledge in every research branch using ionic liquids. Additionally, it discusses the challenges associated with the industrial use of ionic liquids, which require further investigation.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Quantum Science & Technology
Chenlu Wang, Xuegang Li, Huikai Xu, Zhiyuan Li, Junhua Wang, Zhen Yang, Zhenyu Mi, Xuehui Liang, Tang Su, Chuhong Yang, Guangyue Wang, Wenyan Wang, Yongchao Li, Mo Chen, Chengyao Li, Kehuan Linghu, Jiaxiu Han, Yingshan Zhang, Yulong Feng, Yu Song, Teng Ma, Jingning Zhang, Ruixia Wang, Peng Zhao, Weiyang Liu, Guangming Xue, Yirong Jin, Haifeng Yu
Summary: A breakthrough in fabricating a long lifetime transmon qubit was reported, using tantalum films as the base superconductor with a dry etching process. The transmon qubits achieved a best T-1 lifetime of 503 μs, outperforming those fabricated with niobium and aluminum. The stable and highly anisotropic dry etching process of tantalum film shows promise for fabricating medium- or large-scale superconducting quantum circuits with longer lifetimes, meeting the requirements for practical quantum computers.
NPJ QUANTUM INFORMATION
(2022)
Article
Chemistry, Physical
Tawfik A. Saleh
Summary: This review investigates various methods, adsorbents, and catalysts used for the elimination of sulfur compounds, and presents an overview of emerging technologies for ultra deep desulfurization to obtain ultra-low-sulfur fuels. The development of robust adsorbents and nano materials with ideal regeneration approaches is necessary to establish the capabilities of desulfurization processes. This review provides essential references and future directions for developing desulfurization technologies and materials for practical applications.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Liexiao Li, Xiaofeng Sun, Tao Xian, Huajing Gao, Shifa Wang, Zao Yi, Xianwen Wu, Hua Yang
Summary: In this study, hierarchical Bi2O2CO3 nanotubes were synthesized via a one-step hydrothermal route. The effects of reaction time on the morphology and performance of the nanotubes were investigated. The 3-hour-derived nanotubes exhibited the highest photocatalytic performance and were capable of degrading various organic pollutants and purifying simulated industrial wastewater.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
M. M. Bhatti, Hakan F. oztop, R. Ellahi, Ioannis E. Sarris, M. H. Doranehgard
Summary: This article discusses the behavior of diamond and silica nanoparticles suspended in water-based hybrid nanofluids on an exponentially elastic surface, and analyzes the flow characteristics. Mathematical formulations and numerical methods are used to obtain results related to velocity profiles, skin friction coefficients, temperature profiles, and Nusselt numbers, which are compared and validated against previous studies.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Md. Munjur Hasan, Khadiza Tul Kubra, Md. Nazmul Hasan, Mrs Eti Awual, Md. Shad Salman, Md. Chanmiya Sheikh, Ariyan Islam Rehan, Adiba Islam Rasee, R. M. Waliullah, Md. Shahinoor Islam, Shahjalal Khandaker, Aminul Islam, Mohammed Sohrab Hossain, Abdulmohsen K. D. Alsukaibi, Hamed M. Alshammari, Md. Rabiul Awual
Summary: The chemical ligand BSBAE was embedded indirectly on mesoporous silica to fabricate optical composite materials (OCM) for detecting and removing toxic cadmium (Cd(II)) ions from wastewater solutions. The OCM demonstrated high sensitivity and selectivity towards Cd(II) ions in acidic pH conditions (pH 3.50) and showed distinguishable color changes upon the addition of trace levels of Cd(II) ions. Other metal ions did not significantly affect the performance of the OCM, which had a detection limit of 0.32 μg/L and a maximum adsorption capacity of 179.65 mg/g for Cd(II) ions. Cd(II) ions could be successfully desorbed from the saturated OCM using 0.25 M HCl, and the regenerated OCM maintained its selectivity and adsorption capacity. However, the adsorption efficiency slightly decreased after multiple cycles. Therefore, the OCM offers a cost-effective and viable alternative for detecting and removing toxic Cd(II) ions from wastewater.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Sattar Khashkhashi-Moghadam, Sara Ezazi-Toroghi, Melika Kamkar-Vatanparast, Parisa Jouyaeian, Parisa Mokaberi, Helya Yazdyani, Zeinab Amiri-Tehranizadeh, Mohammad Reza Saberi, Jamshidkhan Chamani
Summary: Through various experiments and simulations, the induction of interaction between cyanidin and human serum albumin and human holo transferrin was studied. Fluorescence spectroscopy showed the occurrence of this interaction, while thermodynamic parameters indicated the spontaneous binding of cyanidin to carrier proteins.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
M. A. El-Bindary, M. G. El-Desouky, A. A. El-Bindary
Summary: Efficient date seed activated carbon was prepared through activation treatment using date seed powder. The activated carbon exhibited excellent iodine adsorption performance, surpassing commercial activated carbon. The adsorption conditions of malachite green from aqueous solutions were investigated, and the Langmuir isotherm was found to be suitable for the adsorption process. The adsorption was chemisorption, endothermic, and unpredictable.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Dongying Wang, Zao Yi, Guolu Ma, Bo Dai, Junbo Yang, Jianfa Zhang, Yang Yu, Chao Liu, Xianwen Wu, Qiang Bian
Summary: In this paper, a dual-parameter sensor based on SPR-PCF is proposed for detecting magnetic field and temperature. The sensor has a unique structure and excellent sensing performance, which is important for simultaneous sensing of multiple basic physical parameters.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
Kasimir P. Gregory, Gareth R. Elliott, Hayden Robertson, Anand Kumar, Erica J. Wanless, Grant B. Webber, Vincent S. J. Craig, Gunther G. Andersson, Alister J. Page
Summary: Specific ion effects (SIE) have been studied for over 130 years and are observed in various fields. However, there is currently no general theory to explain ion specificity. This review explores the historical explanations for SIE in water, the properties of key ions, and the behavior of ions at the liquid-vapor interface. It also discusses SIE in mixed electrolytes, nonaqueous solvents, and highly concentrated electrolyte solutions, which are exciting frontiers with relevance to biological and electrochemical applications. The article concludes by summarizing the challenges and opportunities in SIE research and the potential for a general predictive theory.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Article
Chemistry, Physical
M. M. Bhatti, R. Ellahi, Mohammad Hossein Doranehgard
Summary: In recent years, the conversion of solar radiation to thermal energy has received significant attention due to the increasing demand for renewable heat and power. This paper investigates the flow of a hybrid nanofluid through a porous medium and its impact on the performance of solar-thermal systems.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Yin Wang, Yishu Gong, Naipeng Lin, Hu Jiang, Xue Wei, Ning Liu, Xiaodong Zhang
Summary: This study innovatively designed and fabricated a cellulose hydrogel coated nanometer zero-valent iron intercalated montmorillonite composite for the removal of Cr(VI). The composite showed improved dispersity and activity of iron due to the addition of montmorillonite, and the hydrogel provided a mesoporous network structure and functional groups to enhance mass transfer and adsorption degradation reactions.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Jiahui Chen, Guo-Wei Wei
Summary: The BA.2 subvariant of the Omicron variant shows increased infectivity and vaccine escape capability, making it likely to become the next dominant variant and posing a serious threat to existing monoclonal antibodies.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Physical
Katsuhiko Ariga, Yuri Lvov, Gero Decher
Summary: Nanoarchitectonics approaches can produce functional materials through various processes like atom/molecular manipulation, chemical conversion, self-assembly/self-organization, microfabrication, and bio-inspired procedures. The layer-by-layer (LbL) assembly method is a multistep process with the potential to prepare materials with different assembling mechanisms, providing access to superstructures through simple alignment options.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)
Review
Chemistry, Physical
Cornelia S. Buettner, Alice Cognigni, Christian Schroeder, Katharina Bica-Schroeder
Summary: The combination of water and surface-active ionic liquids provides a unique reaction medium for chemical reactions in bulk water. Ionic liquids act as surfactants in aqueous solutions, resulting in solvent systems with unique properties. The use of surface-active ionic liquids is rapidly growing and has applications across various fields of chemistry.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Peilong Xu, Ligong Cui, Shouwu Gao, Na Na, Abdol Ghaffar Ebadi
Summary: The study demonstrates that indium doping can significantly enhance the sensitivity and selectivity of ZnO nanosheets to acetylene gas. The adsorption energy of acetylene increases significantly after indium doping, with the interaction mainly attributed to electrostatic forces. The indium-doped ZnO nanosheets can selectively detect acetylene in the presence of other gases and exhibit a short recovery time.
Article
Chemistry, Physical
Bin Tang, Yi Ren
Summary: This paper proposes an actively tunable and switchable multi-functional terahertz metamaterial device based on a hybrid vanadium dioxide (VO2)-graphene integrated configuration. The functions of the device can be reversibly switched between asymmetric transmission and two different polarization conversions by transiting the phase of VO2. The performance of the device can be actively controlled by adjusting the geometrical parameters and Fermi energy of graphene.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)