Electrochemistry

Article Chemistry, Physical

Green synthesis of DyBa2Fe3O7.988/DyFeO3 nanocomposites using almond extract with dual eco-friendly applications: Photocatalytic and antibacterial activities

Makarim A. Mahdi, Seyede Raheleh Yousefi, Layth S. Jasim, Masoud Salavati-Niasari

Summary: In this study, photocatalytical and antibacterial activities of DyBa2Fe3O7.988/DyFeO3 (Dy-Ba-Fe-O) nanocomposites were investigated as eco-friendly applications. The synthesis method chosen was ultrasound technique to ensure low energy consumption and achieve a pure product with good crystallinity. Natural almond core extract was used as a green reagent. The nanocomposite exhibited a band gap of 2.6 eV, enabling visible-light photocatalysis. Significant degradation of Rhodamin-B dye and strong antibacterial activity against Gram-negative pathogens were observed. The properties of the nanocomposite were characterized by various analyses.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Review Chemistry, Physical

Solar-Driven Hydrogen Production: Recent Advances, Challenges, and Future Perspectives

Hui Song, Shunqin Luo, Hengming Huang, Bowen Deng, Jinhua Ye

Summary: This article provides a comprehensive review of solar H-2 production technologies, with a particular focus on the high solar-to-H-2 conversion efficiency achieved by different routes. Comparative analysis and evaluation are conducted to assess the commercial feasibility of these technologies compared with current industrial H-2 production processes. Additionally, the challenges and prospects of future research on solar H-2 production technologies are presented.

ACS ENERGY LETTERS (2022)

Review Chemistry, Physical

A review on hydrogen production and utilization: Challenges and opportunities

Haris Ishaq, Ibrahim Dincer, Curran Crawford

Summary: This paper critically analyzes the state-of-the-art in blue and green hydrogen production methods, utilization of hydrogen, storage, transportation, distribution, and key challenges and opportunities in the commercial deployment of such systems. It highlights the potential of hydrogen as a new energy vector that can serve multiple purposes blending the roles of fuel energy carrier and energy storage modality.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Review Electrochemistry

Solid-state lithium batteries: Safety and prospects

Yong Guo, Shichao Wu, Yan-Bing He, Feiyu Kang, Liquan Chen, Hong Li, Quan-Hong Yang

Summary: Solid-state lithium batteries have excellent potential energy density, but their safety has been overestimated. This review introduces a safety evaluation methodology and focuses on the structure, conductivity, compatibility, and stability of two types of solid-state electrolytes, discussing their correlation with battery safety. Future avenues for improving the safety of solid-state lithium batteries are also discussed.

ESCIENCE (2022)

Review Chemistry, Physical

Emerging Era of Electrolyte Solvation Structure and Interfacial Model in Batteries

Haoran Cheng, Qujiang Sun, Leilei Li, Yeguo Zou, Yuqi Wang, Tao Cai, Fei Zhao, Gang Liu, Zheng Ma, Wandi Wahyudi, Qian Li, Jun Ming

Summary: Recent research has shown that not only the solid-electrolyte interphase (SEI) layer but also the metal-ion solvation structure and interfacial model in the electrolyte significantly affect the performance of lithium-ion batteries. In this paper, the authors summarize recent studies on the importance of electrolyte solvation structure, develop a quantitative model, and propose an interfacial model to understand the electrode's performance. These findings may lead to a new era beyond the SEI and have implications for the design and improvement of LIBs.

ACS ENERGY LETTERS (2022)

Review Chemistry, Physical

Recent progress on porous carbon and its derivatives from plants as advanced electrode materials for supercapacitors

Guosai Jiang, Raja Arumugam Senthil, Yanzhi Sun, Thangvelu Rajesh Kumar, Junqing Pan

Summary: Porous carbon materials, particularly derived from plants, have shown promising potential in energy storage due to their carbon-rich composition and unique channel structures. Research focuses on synthesis methods, multi-component carbon materials, and improving electrochemical performance, aiming to design electrode materials for efficient electrolyte ion and electron transport. Challenges and trends in utilizing plant-derived carbon materials for supercapacitor application are also highlighted.

JOURNAL OF POWER SOURCES (2022)

Article Biophysics

Recent advancements in optical biosensors for cancer detection

Baljinder Kaur, Santosh Kumar, Brajesh Kumar Kaushik

Summary: Optical biosensors offer rapid, real-time, portable detection with low limits and high sensitivity for diagnosing various types of cancer. Recent advancements focus on the design of biosensors utilizing resonance, scattering, chemiluminescence, luminescence, and other techniques, as well as the development of two-dimensional materials and microfabrication technologies. Surface enhanced Raman spectroscopy and terahertz waves show promise for high specificity detection, while optical fiber platforms may drive the rapid development of biosensors due to their advantages in electromagnetic interference, size, multiplexing, and remote sensing capabilities.

BIOSENSORS & BIOELECTRONICS (2022)

Article Electrochemistry

Phosphated IrMo bimetallic cluster for efficient hydrogen evolution reaction

Xu Guo, Xin Wan, Qingtao Liu, Yongcheng Li, Wenwen Li, Jianglan Shui

Summary: In this study, phosphated IrMo bimetallic clusters supported by macroporous nitrogen-doped carbon were developed as highly efficient alkaline HER catalysts. By tuning the electronic structure and utilizing atom synergies, these catalysts improved the adsorption and desorption abilities of the reactant and product, resulting in low overpotential and high mass activity even with a small amount of Ir. The multilevel design strategy demonstrated in this study effectively improves noble metal atom efficiency.

ESCIENCE (2022)

Review Chemistry, Physical

Global hydrogen development-A technological and geopolitical overview

B. E. Lebrouhi, J. J. Djoupo, B. Lamrani, K. Benabdelaziz, T. Kousksou

Summary: Hydrogen energy will play an important role in the global energy transition and lead to a significant reduction in greenhouse gas emissions in the coming decades. Coordinated efforts and substantial investment are needed to develop the hydrogen value chain on a global scale.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Electrochemistry

Single atomic cobalt electrocatalyst for efficient oxygen reduction reaction

Peng Rao, Daoxiong Wu, Tian-Jiao Wang, Jing Li, Peilin Deng, Qi Chen, Yijun Shen, Yu Chen, Xinlong Tian

Summary: This study presents a single-atom catalyst, Co-SAC/NC, designed via a highly efficient plasma-bombing strategy, which exhibits robust ORR performance in an alkaline medium and excellent battery performance as an air-cathode catalyst in a zinc-air battery. Theoretical calculations reveal the structural evolution of the catalyst and the rate-determining step of the reaction.

ESCIENCE (2022)

Article Chemistry, Physical

Precisely Constructing Orbital Coupling-Modulated Dual-Atom Fe Pair Sites for Synergistic CO2 Electroreduction

Ying Wang, Byoung Joon Park, Vinod K. Paidi, Rui Huang, Yechan Lee, Kyung-Jong Noh, Kug-Seung Lee, Jeong Woo Han

Summary: This study presents a strategy for constructing electrocatalysts with single-atom and dual-site iron anchored on nitrogen-doped carbon matrix, providing new insights into the structure-performance relationship of CO2RR electrocatalysts. The dual-atom electrocatalyst showed enhanced CO Faradaic efficiency and durability compared to single-atom counterparts.

ACS ENERGY LETTERS (2022)

Review Chemistry, Physical

A critical review on the current technologies for the generation, storage, and transportation of hydrogen

Omar Faye, Jerzy Szpunar, Ubong Eduok

Summary: Hydrogen production, storage, and transportation are crucial for achieving a clean and sustainable hydrogen economy. This review discusses the current state and recent advancements in these areas, as well as new techniques to address limitations. The development of modern hydrogen infrastructure is necessary to scale up hydrogen delivery.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Review Electrochemistry

Controlling Li deposition below the interface

Wenzhuo Cao, Quan Li, Xiqian Yu, Hong Li

Summary: This paper examines the behaviors, mechanisms, and influencing factors of Li plating/stripping and proposes general strategies to control Li deposition. It is essential to have comprehensive design strategies for the electrode, electrolyte, and their interface. Three dimensional (3D) anodes and artificial interface engineering can reduce the risk of Li deposition, while electrolyte engineering favors Li transport and suppresses dendrites, serving as the final barrier to uncontrolled Li deposition.

ESCIENCE (2022)

Article Electrochemistry

Large-scale synthesis of N-doped carbon capsules supporting atomically dispersed iron for efficient oxygen reduction reaction electrocatalysis

Hui Yang, Yanfang Liu, Xiaolu Liu, Xiangke Wang, He Tian, Geoffrey I. N. Waterhouse, Paul E. Kruger, Shane G. Telfer, Shengqian Ma

Summary: The large-scale production of stable and active ORR electrocatalysts based on iron was achieved using a core-shell zeolitic imidazolate framework-tannic acid coordination polymer composite (ZIF-8@K-TA) as the catalyst precursor. The resulting H-Fe-Nx-C demonstrated efficient electrocatalytic activity and stability towards the ORR, surpassing the majority of recently reported Fe-N-C catalysts and the standard Pt/C catalyst, with outstanding tolerance to methanol.

ESCIENCE (2022)

Article Chemistry, Physical

Perovskite/CIGS Tandem Solar Cells: From Certified 24.2% toward 30% and Beyond

Marko Jost, Eike Koehnen, Amran Al-Ashouri, Tobias Bertram, Spela Tomsic, Artiom Magomedov, Ernestas Kasparavicius, Tim Kodalle, Benjamin Lipovsek, Vytautas Getautis, Rutger Schlatmann, Christian A. Kaufmann, Steve Albrecht, Marko Topic

Summary: A monolithic perovskite/CIGS tandem solar cell with a certified power conversion efficiency (PCE) of 24.2% is demonstrated. The optimal device stack is determined using optical simulations, and the energy yield is evaluated. The results show the high potential of perovskite/CIGS tandem solar cells in significantly enhancing energy output.

ACS ENERGY LETTERS (2022)

Review Chemistry, Physical

Hydrogen energy storage integrated hybrid renewable energy systems: A review analysis for future research directions

A. Z. Arsad, M. A. Hannan, Ali Q. Al-Shetwi, M. Mansur, K. M. Muttaqi, Z. Y. Dong, F. Blaabjerg

Summary: This paper presents a comprehensive review of highly cited articles on HydESS and provides detailed insights into future directions and applications. The study shows that research on HydESS has expanded rapidly in recent years, with a focus on control and test systems-based methods. The analysis highlights the challenges and issues in the field of HydESS and suggests potential solutions.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Superior hydrogen evolution electrocatalysis enabled by CoP nanowire array on graphite felt

Yuchun Ren, Zerong Li, Biao Deng, Chen Ye, Longcheng Zhang, Yan Wang, Tingshuai Li, Qian Liu, Guanwei Cui, Abdullah M. Asiri, Yonglan Luo, Xuping Sun

Summary: Renewable electricity-powered hydrogen production serves as an attractive alternative to unsustainable industrial processes, yet the large-scale implementation requires efficient and noble-metal-free electrocatalysts. This study introduces a CoP nanowire array on porous graphite felt as a new 3D electrocatalyst for enhanced hydrogen evolution reaction, showing impressive activity and long-term durability under alkaline conditions.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Anion-Diluent Pairing for Stable High-Energy Li Metal Batteries

Chunnan Zhu, Chuangchao Sun, Ruhong Li, Suting Weng, Liwu Fan, Xuefeng Wang, Lixin Chen, Malachi Noked, Xiulin Fan

Summary: This research reports a new method to improve the Coulombic efficiency and inhibit dendritic growth in rechargeable Li metal batteries by introducing fluorinated aromatic diluents into high-concentration electrolytes. The use of this electrolyte provides higher energy density and cycling life without compromising the performance of the battery.

ACS ENERGY LETTERS (2022)

Article Electrochemistry

Advanced polymer-based electrolytes in zinc-air batteries

Qingqing Liu, Ruiting Liu, Chaohui He, Chenfeng Xia, Wei Guo, Zheng-Long Xu, Bao Yu Xia

Summary: Polymer-based electrolytes play a critical role in zinc-air batteries, improving their performance. This article reviews the recent progress in polymer-based electrolytes for zinc-air batteries and proposes future challenges and viable strategies.

ESCIENCE (2022)

Article Electrochemistry

Crack-free single-crystalline Co-free Ni-rich LiNi0.95Mn0.05O2 layered cathode

Lianshan Ni, Ruiting Guo, Susu Fang, Jun Chen, Jinqiang Gao, Yu Mei, Shu Zhang, Wentao Deng, Guoqiang Zou, Hongshuai Hou, Xiaobo Ji

Summary: This study successfully designed a robust single-crystalline, Co-free, Ni-rich cathode material, which has advantages over polycrystalline materials in terms of structural stability and cycling durability and can achieve high discharge capacity and high energy density, with good capacity retention.

ESCIENCE (2022)