Electrochemistry

Article Chemistry, Physical

A Self-Supporting Covalent Organic Framework Separator with Desolvation Effect for High Energy Density Lithium Metal Batteries

Yan Yang, Shiyan Yao, Ziwei Liang, Yucheng Wen, Zhengbo Liu, Yiwen Wu, Jun Liu, Min Zhu

Summary: This study focuses on the application of a self-supporting COF separator in lithium metal batteries. By forming a hydrogen bond network, the separator is able to achieve solvent desolvation and electrolyte aggregation, effectively reducing the side effects of solvent and lithium metal, and demonstrating good cycling stability.

ACS ENERGY LETTERS (2022)

Review Electrochemistry

MXenes: Synthesis strategies and lithium-sulfur battery applications

Teng Zhang, Long Zhang, Yanglong Hou

Summary: This review summarizes the recent advances in MXenes for lithium-sulfur batteries (LSBs), including their structural characterization, synthesis methods, and applications as cathodes, separators, and anodes. The challenges and future directions for research are also discussed.

ESCIENCE (2022)

Article Chemistry, Analytical

Molecularly imprinted polymer based electrochemical sensor for quantitative detection of SARS-CoV-2 spike protein

Akinrinade George Ayankojo, Roman Boroznjak, Jekaterina Reut, Andres Opik, Vitali Syritski

Summary: The study presents an electrochemical sensor based on a molecularly imprinted polymer receptor for quantitatively detecting the S1 subunit of the spike protein of SARS-CoV-2. It has a quick response time and low detection limit, showing promise as a point-of-care testing platform for early diagnosis of COVID-19.

SENSORS AND ACTUATORS B-CHEMICAL (2022)

Article Chemistry, Physical

Direct Electrosynthesis of Urea from Carbon Dioxide and Nitric Oxide

Yanmei Huang, Rong Yang, Changhong Wang, Nannan Meng, Yanmei Shi, Yifu Yu, Bin Zhang

Summary: Electrochemical synthesis of urea is a sustainable strategy that utilizes abundant and low-cost inorganic carbon and nitrogen sources through advanced electrocatalytic processes to achieve efficient urea generation.

ACS ENERGY LETTERS (2022)

Review Electrochemistry

Toward alkaline-stable anion exchange membranes in fuel cells: cycloaliphatic quaternary ammonium-based anion conductors

Jiandang Xue, Junfeng Zhang, Xin Liu, Tong Huang, Haifei Jiang, Yan Yin, Yanzhou Qin, Michael D. Guiver

Summary: This review focuses on the recent advances in alkaline-stable AEM development, with a particular emphasis on the outstanding performance of cQA-based AEMs in alkaline stability. The classification of different types of cQAs and discussions on improving structural design for enhanced AEM stability are highlighted in the article.

ELECTROCHEMICAL ENERGY REVIEWS (2022)

Article Chemistry, Physical

State of health estimation for lithium-ion batteries based on temperature prediction and gated recurrent unit neural network

Zheng Chen, Hongqian Zhao, Yuanjian Zhang, Shiquan Shen, Jiangwei Shen, Yonggang Liu

Summary: Accurate estimation of lithium-ion battery health is crucial for the safety and reliability of electric vehicles. This study proposes a method based on temperature prediction and neural networks to accurately estimate battery health by extracting multi-dimensional features and utilizing a gated recurrent unit neural network for prediction, achieving an error rate within 2.28%.

JOURNAL OF POWER SOURCES (2022)

Article Electrochemistry

Sputtered MoN nanolayer as a multifunctional polysulfide catalyst for high-performance lithium-sulfur batteries

Xin-Yang Yue, Jing Zhang, Jian Bao, Yi-Fan Bai, Xun-Lu Li, Si-Yu Yang, Zheng-Wen Fu, Zhen-Hua Wang, Yong-Ning Zhou

Summary: In this study, MoN nanolayer-decorated multilayer graphene was used as a layer material to suppress the shuttle effect of lithium polysulfides and enhance the redox kinetics in Li-S batteries. After the initial discharge process, the MoN layers break up into independent microreaction units consisting of MoN bodies and MoS2 edges, forming an in situ heterogeneous composite catalyst. The MoN bodies can trap LiPSs and enhance their redox kinetics, while the MoS2 edges weaken the mobility of LiPSs through the anchoring effect. Li-S cells using this interlayer exhibit excellent cycling stability under a high sulfur loading.

ESCIENCE (2022)

Article Chemistry, Analytical

Detection of four alcohol homologue gases by ZnO gas sensor in dynamic interval temperature modulation mode

Fanli Meng, Xue Shi, Zhenyu Yuan, Hanyang Ji, Wenbo Qin, YanBai Shen, Chaoyang Xing

Summary: This paper successfully detected four alcohol homologue gases using a ZnO gas sensor with dynamic temperature modulation method, achieving a recognition accuracy of 97.62% after optimization with decision tree classification algorithm.

SENSORS AND ACTUATORS B-CHEMICAL (2022)

Editorial Material Chemistry, Physical

Large-Area Perovskite-Related Copper Halide Film for High-Resolution Flexible X-ray Imaging Scintillation Screens

Yang Zhou, Xiaojia Wang, Tengyue He, Haoze Yang, Chen Yang, Bingyao Shao, Luis Gutierrez-Arzaluz, Osman M. Bakr, Yuhai Zhang, Omar F. Mohammed

Summary: Flexible copper halide films with outstanding mechanical stability, excellent film uniformity, nearly 100% photo-luminescence quantum yields, and resistance to water and heat were fabricated. Scintillators based on these films exhibit superior scintillation performance with a detection limit as low as 48.6 nGy/s and 17 lp/mm X-ray imaging resolution, representing the highest imaging resolution for powder-based screens.

ACS ENERGY LETTERS (2022)

Review Chemistry, Physical

A review on biomass based hydrogen production technologies

Dan Bahadur Pal, Arvind Singh, Ashish Bhatnagar

Summary: This paper examines the development of bio-hydrogen technology as a sustainable and environmentally friendly energy source, discussing key chemical derivatives of biomass and biological processes. The challenges of bio-H2 production and the costs and benefits of different techniques are also explored.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Analytical

Metal oxide gas sensors for detecting NO2 in industrial exhaust gas: Recent developments

Qingting Li, Wen Zeng, Yanqiong Li

Summary: This article reviews the NO2 gas sensor based on metal oxides. It discusses the hazards of NO2, the disadvantages of chemiresistive sensors based on metal oxides, and different sensitive materials. It also explores NO2 gas sensors based on metal oxides from various aspects such as morphology, preparation, modification, doping, and composite.

SENSORS AND ACTUATORS B-CHEMICAL (2022)

Article Electrochemistry

PANI-MnO2 and Ti3C2Tx (MXene) as electrodes for high-performance flexible asymmetric supercapacitors

Yudi Wei, Wenlong Luo, Xue Li, Zhongtai Lin, Chunping Hou, Mingliang Ma, Jianxu Ding, Tingxi Li, Yong Ma

Summary: In this study, PANI and MnO2 were synthesized on carbon cloth using electrochemical polymerization, resulting in improved specific capacitance of the material. An asymmetric supercapacitor was assembled to broaden its potential range, and the device's ductility was explored to resist external forces. The research enhances the practical application of energy storage devices.

ELECTROCHIMICA ACTA (2022)

Review Chemistry, Physical

Hydrogen production through renewable and non-renewable energy processes and their impact on climate change

Muhammad Amin, Hamad Hussain Shah, Anaiz Gul Fareed, Wasim Ullah Khan, Eunhyea Chung, Adeel Zia, Zia Ur Rahman Farooqi, Chaehyeon Lee

Summary: Urbanization and population growth have significantly impacted global energy demands. The use of non-renewable fossil fuel-based energy infrastructure leads to air pollution, global warming, greenhouse gas emissions, acid rain, diminishing energy resources, and environmental degradation. This necessitates the exploration of alternative energy sources. Hydrogen, as an efficient energy carrier, has gained scientific attention as an alternative fuel to meet energy demands. This review focuses on hydrogen production from renewable sources (such as biomass, solar, wind, geothermal, and algae) and conventional non-renewable sources (including natural gas, coal, nuclear, and thermochemical processes). Additionally, the cost analysis for hydrogen production from each energy source is discussed. Finally, the environmental impact and implications of these hydrogen production processes are summarized.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Review Electrochemistry

Effects of Crystallinity and Defects of Layered Carbon Materials on Potassium Storage: A Review and Prediction

Xiaoxu Liu, Tianyi Ji, Hai Guo, Hui Wang, Junqi Li, Hui Liu, Zexiang Shen

Summary: This review discusses the key structural factors affecting potassium storage in LCMs, establishes a structure-property database, and systematically analyzes the effects of structural parameters on potassium storage properties. It provides a foundation for future exploration and applications in the field.

ELECTROCHEMICAL ENERGY REVIEWS (2022)

Review Chemistry, Analytical

Influence of major parameters on the sensing mechanism of semiconductor metal oxide based chemiresistive gas sensors: A review focused on personalized healthcare

Sagnik Das, Subhajit Mojumder, Debdulal Saha, Mrinal Pal

Summary: In this review, the significant effects of various parameters on the sensing behavior of semiconductor metal oxide (SMO) based chemiresistive gas sensors have been discussed in detail. The study systematically reviewed the impact of different material and operating condition aspects on the gas sensing performance of SMO sensors. The importance of long-term stability and high-throughput synthesis techniques in practical applications was emphasized, and the future prospects of SMO-based sensors in personalized healthcare were briefly outlined.

SENSORS AND ACTUATORS B-CHEMICAL (2022)

Article Electrochemistry

A potential-driven switch of activity promotion mode for the oxygen evolution reaction at Co3O4/NiOxHy interface

Wang Wang, Zixu Wang, Youcheng Hu, Yucheng Liu, Shengli Chen

Summary: In this study, a newly proposed kinetic model was used to investigate the promotion mechanism of the oxygen evolution reaction (OER) for Co3O4 interfaced with nickel hydroxides (NiOxHy). The results revealed that depending on the electrode potential, the OER kinetics at the designed interface between Co3O4 and NiOxHy are boosted in different ways, leading to a lower onset potential and a low Tafel slope.

ESCIENCE (2022)

Article Biophysics

Fully integrated flexible biosensor for wearable continuous glucose monitoring

Xiaofeng Jin, Guanhua Li, Tailin Xu, Lei Su, Dan Yan, Xueji Zhang

Summary: Continuous glucose monitoring platform with optimized linear range and long-term stability was developed using a biocompatible conjugated polymer. The system included a small design with signal conditioning, programmable electrochemical chip, and wireless connection. Biocompatibility tests and animal experiments confirmed successful in vivo blood glucose monitoring.

BIOSENSORS & BIOELECTRONICS (2022)

Article Chemistry, Physical

Solvent-Free Approach for Interweaving Freestanding and Ultrathin Inorganic Solid Electrolyte Membranes

Changhong Wang, Ruizhi Yu, Hui Duan, Qingwen Lu, Qizheng Li, Keegan R. Adair, Danni Bao, Yang Liu, Rong Yang, Jiantao Wang, Shangqian Zhao, Huan Huang, Xueliang Sun

Summary: This study successfully fabricated representative SE membranes with thin thickness and high room-temperature ionic conductivity using PTFE fibrilization technology. The all-solid-state pouch cells prepared with this technology exhibited high capacity and cycling stability.

ACS ENERGY LETTERS (2022)

Article Chemistry, Physical

Green hydrogen standard in China: Standard and evaluation of low-carbon hydrogen, clean hydrogen, and renewable hydrogen

Wei Liu, Yanming Wan, Yalin Xiong, Pengbo Gao

Summary: Building a low-carbon and clean hydrogen supply system has become a global consensus with the proposal of carbon neutral goals in various countries, the deepening of global action on climate change, and the acceleration of green economy recovery in the post epidemic era. The standards for green hydrogen have been discussed globally, and China has issued the first formal green hydrogen standard, providing calculation methods for greenhouse gas emissions of different hydrogen production paths.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Aminouracil-assisted synthesis of CoFe decorated bougainvillea-like N-doped carbon nanoflowers for boosting Zn-air battery and water electrolysis

Shi-Yi Lin, Yu-Ping Chen, Ying Cao, Lu Zhang, Jiu-Ju Feng, Ai-Jun Wang

Summary: In this study, highly efficient and cost-effective non-precious metal-based electrocatalysts were synthesized for oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER). The catalyst exhibited improved performance with positive onset potential, small overpotential, and excellent stability. It shows great potential for applications in metal-air batteries and water electrolysis.

JOURNAL OF POWER SOURCES (2022)