Chemistry, Multidisciplinary

Article Chemistry, Multidisciplinary

Current perspectives on industrial application of microbial carotenoid as an alternative to synthetic pigments

Priya Sundararajan, Shanmuga Priya Ramasamy

Summary: This review provides insights into the production of carotenoids using microorganisms, summarizing the biosynthetic pathways involved in microbial synthesis and highlighting the production, extraction, and purification strategies. It aims to expedite the commercialization of microbial carotenoids.

SUSTAINABLE CHEMISTRY AND PHARMACY (2024)

Article Chemistry, Multidisciplinary

Ultra-strong penetrating and GSH-responsive oral drug delivery system improved therapeutic effect of gemcitabine for pancreatic tumors

Xu Zhang, Kejian Shi, Jiahui Mao, Kerou Mao, Yangrui Jia, Jiakun Zhang, Qingzhen Wang, Ru Bai, Fene Gao, Shihui Liu, Mengyu Guo, Fenglan Qin, Shengmin Li, Chunying Chen, Huige Zhou, Jing Liu, Fulin Chen

Summary: Compared with vein injection, oral administration is a preferred non-invasive and self-help treatment option for cancer therapy. However, the harsh gastrointestinal tract and biological barriers limit the stability and efficiency of oral drug delivery systems. To overcome these challenges, researchers have developed Cyssome, a drug delivery platform that can maintain stability in harsh environments, penetrate biological barriers, and improve drug release and bioavailability.

NANO TODAY (2024)

Article Chemistry, Multidisciplinary

Enhancement of microwave absorption performance of FeSiCr magnetic powder by dielectric polarization modulation

Weiwei Dong, Shuqi Shen, Lei Wang, Wenmiao Zhang, Hongzhang Du, Yifeng Hu, Sajjad Ur Rehman, Tongxiang Liang

Summary: The Fe3O4@C@FeSiCr composite was successfully prepared by compounding flaky FeSiCr magnetic powder with an organo-metallic frameworks (MIL-88(Fe)), and adjusting the heat treatment temperature regulated the dielectric polarization characteristics of the material. It was found that the composite material exhibited optimal absorbing performance at 700 degrees C, with a minimum reflection loss of -35.71 dB at 5.68 GHz.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

The thermoelectric properties of novel two-dimensional semiconductor ZrNBr alloyed with Fluorine: A DFT plus U survey

Fatemeh Shirvani, Zahra Razavifar

Summary: This study investigates the thermoelectric properties of novel two-dimensional transition metal halide alloyed with fluorine using density functional theory and Hubbard's potential. The results suggest that these materials have potential applications in thermoelectric devices under appropriate conditions.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Enhancing the electrochemical properties of Na2Mn2P3O9N by partial substitution at Mn site: A first-principles study

Vishnu Sudarsanan, Anu Maria Augustine, P. Ravindran

Summary: This study addresses the low electronic conductivity issue in nitridophosphate-based materials by partially substituting transition metal at the manganese site. The findings suggest that partial substitution of copper/silver at the manganese site could be a promising strategy for improving the electronic conductivity of nitridophosphate materials without compromising their beneficial properties, making them suitable for use in higher energy density Na-ion batteries.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Persulfate activation over CoFe2O4/CuS for degradation of Orange II under visible light

Yixing Hao, Fang Zhu, Hao Cheng, Sridhar Komarneni, Jianfeng Ma

Summary: A magnetic porous composite catalyst synthesized from CoFe2O4 and CuS showed high degradation efficiency for organic pollutants under visible light conditions, using non-radical degradation as the main pathway.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Biomass-based porous carbon from trachycarpus fortunei silk with the hierarchical oxygen-enriched structure for high performance flexible all-solid-state supercapacitor

Qin Wang, Hong Zheng, Yurun Zhang, Yuting Huang, Wenquan Li, Wenjing Huang, Jing Xiang, Peng Yuan, Hao Xue, Shuya Wang, Yun Zhou, Wei Lu

Summary: In this study, hierarchical oxygen-enriched porous carbon was synthesized using trachycarpus fortunei silk waste as the raw material. The carbon material exhibited excellent electrochemical properties, including high specific capacitance and remarkable cycling stability. The assembled supercapacitor device showed a high energy density and superior mechanical flexibility.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Photonic and phononic properties of oriented 5 nm diameter tellurium nanowires

Vladimir V. Poborchii, Victor A. Sachkov, Alexander A. Shklyaev, Alexander V. Fokin, Pavel I. Geshev

Summary: This study investigates the polarized optical absorption and Raman spectra of -5 nm diameter tellurium nanowires confined in chrysotile asbestos nanotubes. The results show a strong interaction between the nanowires and light polarized parallel to the nanowires, while a weaker interaction is observed for light polarized perpendicular to the nanowires. This has significant implications for photonic and photo-electric applications.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Palladium-catalyzed multi components oxy-aminofluorination and aminofluorination of gem-difluoroalkenes

Fen Wu, Xin Li, Junbiao Chang, Dachang Bai

Summary: In this study, a palladium-catalyzed intermolecular aminofluorination and oxy-aminofluorination method was developed, which enables efficient synthesis of high-value amine compounds with fluoroalkyl-substituents and selective transformation of easily available ether compounds.

CHINESE CHEMICAL LETTERS (2024)

Article Chemistry, Multidisciplinary

Natural polysaccharide-based smart CXCR4-targeted nano-system for magnified liver fibrosis therapy

Liqiong Sun, Xinping Luo, Chenxi Zhou, Zhanwei Zhou, Minjie Sun

Summary: The study designed a drug delivery system that can specifically deliver anti-fibrosis drugs to activated hepatic stellate cells and achieve on-demand drug release and effective fibrosis reversion. It was found that the addition of a CXCR4 antagonist in the system enhanced the targeting efficiency of the drug and resulted in synergistic anti-fibrosis effect.

CHINESE CHEMICAL LETTERS (2024)

Article Chemistry, Multidisciplinary

Preparing cyclic polymers at high concentrations via self-folding cyclization technique by adjusting the contents of hydrophilic units in linear precursors

Hao Zha, Zuowei Wang, Chao Liu, Chunyan Hong

Summary: Cyclic polymers were efficiently constructed by self-folding cyclization technique at high concentrations. By adjusting the content of the hydrophilic segments in linear precursors, cyclic polymers with high purity can be generated at high polymer concentrations.

CHINESE CHEMICAL LETTERS (2024)

Article Chemistry, Multidisciplinary

Anion cascade reactions III: Synthesis of 3-isoquinuclidone bridged polycyclic lactams

Zhiguo Zhang, Bingbing Shi, Xiyang Cao, Nana Ma, Hao Wu, Xingjie Zhang, Guisheng Zhang

Summary: Bridged polycyclic lactams are important structural units in organic functional materials, natural products, and pharmaceuticals. A flexible and efficient anion cascade reaction was developed for the preparation of bridged polycyclic lactams. The reaction showed good yields of various highly substituted bridged polycyclic lactams.

CHINESE CHEMICAL LETTERS (2024)

Article Chemistry, Multidisciplinary

Effects of biosynthesized ZnO nanoparticles on oxidative stress parameters in Saccharomyces cerevisiae

Ankita Nandi, Ritam Mehera, Moumita Mandal, Paramesh Chandra, Swapan K. Mandal, Naznin Ara Begum, Chandan K. Jana, Nilanjana Das

Summary: In this study, stable biogenic ZnO nanoparticles were successfully synthesized using a biosynthesis method, and their effects on oxidative stress parameters in Saccharomyces cerevisiae were investigated. The results demonstrate that high concentrations of ZnO nanoparticles may induce oxidative stress conditions, suggesting caution in their extensive use.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Interactions of phenol and benzaldehyde in electrocatalytic upgrading process

Lan Liang, Chuanbin Wang, Xukai Lu, Yunan Sun, Beibei Yan, Ning Li, Guanyi Chen, Li'an Hou

Summary: This study investigates the interactions between phenol and benzaldehyde in the ECH process through experiments and theoretical calculations. The results show that phenol can accelerate the conversion of benzaldehyde, while benzaldehyde inhibits the conversion of phenol. The research provides a theoretical basis for the application of ECH in practical bio-oil upgrading.

CHINESE CHEMICAL LETTERS (2024)

Article Chemistry, Multidisciplinary

Rapid analysis of metal ions and organic compounds in strong acidic solutions by nano-ESI mass spectrometry

Jiaquan Xu, Ting Li, Zhendong Yu, Lili Song, Xiu-Xiu Xu, Hui Li

Summary: In this study, a simple method using nano-ESI MS was developed for rapid analysis of metal ions and organic compounds in strong acidic solutions. The method offers low sample consumption, high speed, high sensitivity, and high accuracy, and shows great application potential in fields such as gastric juice analysis, monitoring of acid-catalyzed reactions, and micro-area analysis of ores.

CHINESE CHEMICAL LETTERS (2024)

Article Chemistry, Multidisciplinary

Sodium lignosulfonate-modulated small-size BiOCl-C nanosheets with excellent visible light degradation of organic pollutant

Yongli Yin, Yiming Sun, Tiantian Jiao, Haifeng Zhou, Peng Liang

Summary: In this study, BiOCl-C composites were prepared using SLS as the carbon source. The addition of SLS effectively reduced the size of BiOCl-C nanosheets, with the best size and photocatalytic activity achieved at an SLS dosage of 0.4 g. Compared to pure BiOCl, the smaller BiOCl-C nanosheets exhibited enhanced degradation of RhB and could eliminate 90.2% of RhB under light conditions. This improvement was attributed to the introduction of carbon material, which increased the specific surface area and reduced electron-hole recombination. Additionally, the BiOCl-C composites demonstrated higher electron mobility under the small size effect, leading to improved photocatalytic degradation efficiency.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Phase formation in the NiSO4-CoSO4-H2O system and specifications in the structures of single crystals of CoxNi(2-x)(SO4)212H2O

Vladimir A. Komornikov, Nataliya I. Sorokina, Natalia A. Vasilyeva, Diana S. Matveeva, Alexey E. Voloshin

Summary: This study investigated the conditions for phase formation in the ternary water-salt system NiSO4-CoSO4-H2O at 25 degrees C, which is the first step towards creating structurally perfect mixed crystals CoxNi(2-x)(SO4)(2)12H(2)O. The regions of crystallization for tetragonal NiSO46H(2)O and monoclinic solid solution of CoxNi(2-x)(SO4)(2)12H(2)O were determined based on the NiSO4:CoSO4 mass ratio. Additionally, a set of CoxNi(2-x)(SO4)(2)12H(2)O single crystals were obtained in the range of 0.05 <= x <= 1.95, and the crystal structures of samples with x values of 1.5, 1.13, and 0.56 were studied. The CoxNi(2-x)(SO4)(2)12H(2)O crystals are solid solutions based on the crystal structure of CoSO46H(2)O, and they showed significant decreases in transmission band intensity in the visible region of the spectrum, making them promising materials for optical filters in photonics.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

The adsorption of ethyl formate on CaO: A DFT study

P. Bechthold, J. Juan, A. Juan, J. M. Marchetti

Summary: The adsorption of ethyl formate on the CaO (001) surface has been analyzed using DFT with Van der Waals corrections. The study reveals a possible adsorption site with a high adsorption energy, and the molecular structure of ethyl formate undergoes stabilization upon adsorption.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Enhancing Ag2MoO4 catalytic activity: An investigation on synthesis, characterization, and application in catalytic ozonation reactions

Daniela G. Della Rocca, Fernanda C. Fraga, Agenor De Noni Junior, Rosely A. Peralta, Regina F. P. M. Moreira

Summary: This study successfully synthesized the alpha-phase of silver molybdate and investigated the relationship between synthesis conditions and optical-textural properties. The results showed that synthesis conditions significantly influenced the formation of the alpha-phase and its optical properties. Increasing pH had a negative effect on textural properties and crystalline phase distribution, while the interaction between PVP concentration and pH improved optical properties.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)

Article Chemistry, Multidisciplinary

Nanostructured Al-doped maghemite: A low-cost and eco-friendly material tested for methylene blue removal from water and as an accelerator in ammonium nitrate decomposition

A. F. Cabrera, C. E. Rodriguez Torres, S. J. Stewart

Summary: Maghemite's properties can be enhanced by doping with other metals for use as removable and reusable catalysts or photocatalysts. Aluminum doping led to decreased cell parameters and grain size, as well as decreased saturation magnetization. The optical band gaps red-shifted and the composition with x=0.33 showed the best photocatalytic efficiency.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2024)