Chemistry, Inorganic & Nuclear

Article Chemistry, Inorganic & Nuclear

In situ construction of a C3N5 nanosheet/Bi2WO6 nanodot S-scheme heterojunction with enhanced structural defects for the efficient photocatalytic removal of tetracycline and Cr(vi)

Shijie Li, Mingjie Cai, Yanping Liu, Junlei Zhang, Chunchun Wang, Shaohong Zang, Youji Li, Peng Zhang, Xin Li

Summary: This study investigates the performance of C3N5/Bi2WO6 photocatalyst with S-scheme heterojunction in water decontamination, and finds that it exhibits higher activity and more structural defects than single C3N5 and Bi2WO6, leading to improved charge separation and generation of more active species.

INORGANIC CHEMISTRY FRONTIERS (2022)

Review Chemistry, Inorganic & Nuclear

A critical review on graphitic carbon nitride (g-C3N4)-based materials: Preparation, modification and environmental application

Jianlong Wang, Shizong Wang

Summary: This review systematically analyzes and summarizes the recent advances in graphitic carbon nitride (g-C3N4)-based composites, including preparation, characterization, modification, and environmental application. The focus is on the modification mechanisms and environmental applications. Concluding remarks and perspectives for further study are provided.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Application of MOF materials as drug delivery systems for cancer therapy and dermal treatment

Shadpour Mallakpour, Elham Nikkhoo, Chaudhery Mustansar Hussain

Summary: Metal-organic frameworks (MOFs) have gained attention for their adjustable pore sizes, large surface area, and various functionalities, making them suitable for applications in energy storage, CO2 adsorption, catalysis, drug storage, and release.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Supports promote single-atom catalysts toward advanced electrocatalysis

Hui Xu, Yitao Zhao, Qing Wang, Guangyu He, Haiqun Chen

Summary: Single-atom catalysts offer high reactivity and selectivity, but are susceptible to sintering and agglomerating. Introducing appropriate supports can optimize the local coordination environment and electronic properties, preventing sintering.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Portable electrochemical sensing methodologies for on-site detection of pesticide residues in fruits and vegetables

Reddicherla Umapathi, Seyed Majid Ghoreishian, Sonam Sonwal, Gokana Mohana Rani, Yun Suk Huh

Summary: Due to over application of synthetic pesticides, pesticide residues pose an increasing threat to ecosystems and human health. Electrochemical sensor and biosensor platforms have emerged as powerful analytical methods for detecting pesticide residues, offering advantages such as synergistic aspects, systematic fabrication procedure, ease of detection, sensitivity, and selectivity. Additionally, portable electrochemical devices have been developed for on-site detection of pesticide residues.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Bimetallic metal-organic frameworks and MOF-derived composites: Recent progress on electro- and photoelectrocatalytic applications

Yingtang Zhou, Reza Abazari, Jing Chen, Muhammad Tahir, Anuj Kumar, Riyadh Ramadhan Ikreedeegh, Ekta Rani, Harishchandra Singh, Alexander M. Kirillov

Summary: MOFs have gained attention as versatile electro- and photoelectrocatalytic platforms, offering advantages such as high surface area, porosity, and structural tunability. Bimetallic MOFs and their composites show improved electrical conductivity and electrochemical activity, making them promising for sustainable energy conversion.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Cellulose-metal organic frameworks (CelloMOFs) hybrid materials and their multifaceted Applications: A review

Hani Nasser Abdelhamid, Aji P. Mathew

Summary: Cellulose-MOFs (CelloMOFs) are hybrid materials that combine cellulosic materials with metal-organic frameworks, offering a range of properties for applications in water remediation, air purification, gas storage, sensing/biosensing, and biomedicine. Their potential includes efficient adsorption for removing contaminants in water, catalytic applications for organic pollutants, air purification by removing greenhouse gases, and biomedical applications such as antibacterial and drug delivery. This review provides a synthesis, characterization, and overview of the applications of CelloMOFs materials, highlighting challenges and future prospects for researchers and scientists.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Advanced photocatalysts for uranium extraction: Elaborate design and future perspectives

Tao Chen, Kaifu Yu, Changxue Dong, Xin Yuan, Xiang Gong, Jie Lian, Xin Cao, Mingzhe Li, Li Zhou, Baowei Hu, Rong He, Wenkun Zhu, Xiangke Wang

Summary: Nuclear energy is a promising energy source to replace traditional fossil fuels due to its high energy density and carbon-free emission. However, the limited storage of uranium ore and uranium-containing wastewater pose challenges to the sustainable development of nuclear energy. Therefore, extracting and recycling uranium from seawater and wastewater is necessary for the sustainable development of nuclear energy and environmental protection.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Covalent organic frameworks promoted single metal atom catalysis: Strategies and applications

Vasudha Hasija, Shilpa Patial, Pankaj Raizada, Aftab Aslam Parwaz Khan, Abdullah M. Asiri, Quyet Van Le, Van-Huy Nguyen, Pardeep Singh

Summary: This review discusses the strategic synthesis, advanced characterization, and catalytic applications of COF-based SACs, highlighting the potential of COFs for fulfilling the prerequisites of SACs formation and their performance in catalytic energy-related applications. It also presents a critical discussion on the strategic synthesis of COF-based SACs and the challenges, foresighted ideas, and future perspectives for COF-based SACs.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Insight into the electrolyte strategies for aqueous zinc ion batteries

Huihui Yan, Xikun Zhang, Zhengwei Yang, Maoting Xia, Chiwei Xu, Yiwen Liu, Haoxiang Yu, Liyuan Zhang, Jie Shu

Summary: This review discusses the electrolyte strategies for rechargeable aqueous zinc ion batteries (AZIBs), including diverse electrolytes, concentration choices, and flexible hydrogel electrolytes, as well as prospects for biocompatible or biodegradable bio-electrolytes as potential candidates.

COORDINATION CHEMISTRY REVIEWS (2022)

Article Chemistry, Inorganic & Nuclear

CeO2 Particles Anchored to Ni2P Nanoplate for Efficient Photo-catalytic Hydrogen Evolution

Teng Yan, Xiaojie Zhang, Hua Liu, Zhiliang Jin

Summary: Photocatalytic hydrogen evolution can convert intermittent and dispersive solar energy into hydrogen with high energy density. This experiment modifies the performance of the catalyst by introducing cocatalyst and morphology control, and has reference significance for the design of efficient and environmentally friendly photocatalysts.

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY (2022)

Article Chemistry, Inorganic & Nuclear

In-situ Construction of Sulfur-doped g-C3N4/defective g-C3N4 Iso-type Step-scheme Heterojunction for Boosting Photocatalytic H2 Evolution

Jing Zou, Guodong Liao, Jizhou Jiang, Zhiguo Xiong, Saishuai Bai, Haitao Wang, Pingxiu Wu, Peng Zhang, Xin Li

Summary: A novel isotype step-scheme heterojunction with rich defects and catalytically active sites is successfully developed by polymerizing N,N-dimethylformamide (DMF) and urea with sulfur (S) powder. The simultaneous introduction of S-doping and defects greatly improves the separation, transfer, and recombination efficiency of photo-excited electron-hole pairs.

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY (2022)

Article Chemistry, Inorganic & Nuclear

A 2D Porous Zinc-Organic Framework Platform for Loading of 5-Fluorouracil

Liang Qin, Fenglan Liang, Yan Li, Jiana Wu, Shiyuan Guan, Meiyin Wu, Shiling Xie, Manshi Luo, Deyun Ma

Summary: A hydrostable 2D Zn-based MOF with good water and thermal stability was synthesized and characterized. It showed potential for controlled drug release and exhibited low cytotoxicity towards cells and zebrafish.

INORGANICS (2022)

Review Chemistry, Inorganic & Nuclear

Biomedical Applications of Functionalized Gold Nanoparticles: A Review

Kazem Nejati, Mehdi Dadashpour, Tohid Gharibi, Hassan Mellatyar, Abolfazl Akbarzadeh

Summary: Metal nanoparticles, especially gold nanoparticles, have unique physicochemical properties that make them valuable for biomedical applications such as biosensing, cancer therapy, and drug delivery. Their large surface area allows for functionalization with biological molecules, making them a promising carrier for targeted drug delivery.

JOURNAL OF CLUSTER SCIENCE (2022)

Review Chemistry, Inorganic & Nuclear

Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts

Abebe Reda Woldu, Zanling Huang, Pengxiang Zhao, Liangsheng Hu, Didier Astruc

Summary: The article provides a brief overview of CO2RR and discusses recent advances in improving the activity and selectivity of Cu-based nanomaterials for CO2 reduction to multi-carbon products. It reviews different types of Cu nanoparticles, Cu nanocrystals with low- and high-index facets, and other Cu-based nanostructures for CO2RR. The aim of the review is to offer new insights and prospects for future research on CO2RR selectivity using Cu-based catalysts.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Metal-organic frameworks with different dimensionalities: An ideal host platform for enzyme@MOF composites

Yingjie Du, Xiaotong Jia, Le Zhong, Yi Jiao, Zhijin Zhang, Ziyuan Wang, Yuxiao Feng, Muhammad Bilal, Jiandong Cui, Shiru Jia

Summary: This review presents the contemporary advances in the development of enzyme@MOF composites with different dimensionalities. The synthesis strategies, interaction between enzymes and MOFs, and potential applications are discussed. This work provides helpful insights into the fundamental research and applications of enzyme@MOF composites.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

MXene based emerging materials for supercapacitor applications: Recent advances, challenges, and future perspectives

Subhasree Panda, Kalim Deshmukh, Jayaraman Theerthagiri, Sivakumar Manickam, S. K. Khadheer Pasha, Myong Yong Choi

Summary: With the advancement of technology, there has been an increasing demand for high-capacity energy storage devices with durability, low production cost, and flexibility. MXene, as the most prominent material today, has a wide range of applications in the field of energy storage. This article reviews the recent advances of MXene for fabricating electrochemical energy storage devices using supercapacitors as its power source, and discusses its structure, synthesis methods, unique properties, and their effect on electrochemical performance. The article also highlights the recent progress in MXene composite-based supercapacitors.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Modified UiO-66 as photocatalysts for boosting the carbon-neutral energy cycle and solving environmental remediation issues

Hongda Liu, Min Cheng, Yang Liu, Gaoxia Zhang, Ling Li, Li Du, Bo Li, Sa Xiao, Guangfu Wang, Xiaofeng Yang

Summary: UiO-66, a water-resistant zirconium-based metal-organic framework, shows excellent environmental resistances and can be used in photocatalytic applications. The photoresponse range and charge separation efficiency of UiO-66 can be significantly improved by rational design and adjustment. This review provides an overview of the modification and design of UiO-66 and its applications in various fields, highlighting the reaction mechanisms.

COORDINATION CHEMISTRY REVIEWS (2022)

Review Chemistry, Inorganic & Nuclear

Nickel-based bimetallic battery-type materials for asymmetric supercapacitors

Yanqun Tang, Wenhan Guo, Ruqiang Zou

Summary: The development of advanced energy storage systems, such as supercapacitors with ideal capacity and durability, is crucial for mitigating intermittency issues associated with natural energy resources. By leveraging the synergistic effects of electrode materials, asymmetric supercapacitors are able to achieve a large voltage window while overcoming traditional supercapacitors' energy storage limitations.

COORDINATION CHEMISTRY REVIEWS (2022)

Article Chemistry, Inorganic & Nuclear

Ambient electrochemical N2-to-NH3 conversion catalyzed by TiO2 decorated juncus effusus-derived carbon microtubes

Haijun Chen, Jie Liang, Kai Dong, Luchao Yue, Tingshuai Li, Yongsong Luo, Zhesheng Feng, Na Li, Mohamed S. Hamdy, Abdulmohsen Ali Alshehri, Yan Wang, Xuping Sun, Qian Liu

Summary: In this study, a hybrid catalyst of TiO2 and juncus effusus-derived carbon microtubes with a three-dimensional cross-linked hollow tubular structure is proposed for efficient electrocatalytic conversion of N-2 to NH3 at ambient conditions. The catalyst shows a high NH3 yield and faradaic efficiency in 0.1M Na2SO4, along with superior electrochemical and structural stability.

INORGANIC CHEMISTRY FRONTIERS (2022)