4.8 Article

Magnetically recyclable magnetite-palladium (Nanocat-Fe-Pd) nanocatalyst for the Buchwald-Hartwig reaction

Journal

GREEN CHEMISTRY
Volume 16, Issue 7, Pages 3494-3500

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc00558a

Keywords

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Funding

  1. Fundacao para a Ciencia e a Tecnologia [PEst-C/EQB/LA0006/2011, PEst-C/CTM/LA0025/2011, PEst-OE/FIS/UI0068/2011]
  2. Operational Program Research and Development for Innovations - European Regional Development [CZ.1.05/2.1.00/03.0058]
  3. Operational Program Education for Competitiveness - European Social Fund of the Ministry of Education, Youth and Sports [CZ.1.07/2.3.00/30.0041]
  4. Technology Agency of the Czech Republic - Competence Centers [TE01020218]
  5. [SFRH/BPD/64934/2009]

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The immobilization of Pd on the magnetite surface afforded Nanocat-Fe-Pd using inexpensive precursors and its catalytic role in the Buchwald-Hartwig reaction for arylation of amines and amides was investigated; C-N bond formation was achieved in moderate to excellent yields and the catalyst could be separated and recycled up to five cycles by magnetic decantation without a significant loss in yield.

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