Journal
GREEN CHEMISTRY
Volume 16, Issue 3, Pages 1552-1559Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41919c
Keywords
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Funding
- ICIQ Foundation
- ICREA
- Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2011-27385, CTQ2008-00947/BQU, CTQ2012-38594-C0201, DEC 2009SGR623]
- MINECO for a Juan de la Cierva postdoctoral fellowship
- MECD for an FPU fellowship
- ICREA Funding Source: Custom
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The development of a heterogeneous one-component bifunctional catalyst system able to catalyse the conversion of carbon dioxide and oxiranes to organic cyclic carbonates at low temperature (45 degrees C) is reported. The bifunctional system can be easily recycled and reactivated when required. When compared with other heterogeneous organocatalysts for the same transformation, the reported catalyst is active at much milder temperatures, thus emphasising the optimal sustainability profile of the new catalyst system.
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