4.8 Article

Production of bio-derived ethyl lactate on GaUSY zeolites prepared by post-synthetic galliation

Journal

GREEN CHEMISTRY
Volume 16, Issue 2, Pages 589-593

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc40766g

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Funding

  1. Swiss National Science Foundation [200021-140496]
  2. Swiss National Science Foundation (SNF) [200021_140496] Funding Source: Swiss National Science Foundation (SNF)

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Galliation of USY zeolites in alkaline media creates tetra-coordinated Lewis-acid centres linked to the framework which display outstanding selectivity in the isomerisation of dihydroxyacetone to ethyl lactate and full reusability. This simple and affordable post-synthetic route enables to tune the amount of Lewis acidity in the zeolite and has great potential for application in related biomass conversions.

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