Journal
GREEN CHEMISTRY
Volume 16, Issue 6, Pages 3230-3236Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc00383g
Keywords
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Funding
- Ministry of Education, Science, Sports and Culture of Japan [24350075]
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Dispersible self-assembled boronate polymers can serve as support materials for metal nanoparticle catalysts. As a proof-of-concept, catalytic systems for the chemoselective hydrogenation of cinnamaldehyde (CA) were prepared by the NaBH4 reduction of PdCl42- and AuCl4- in methanol, in the presence of polyethyleneimine (PEI)-coated boronate particles (BPs) composed of polymeric 3-benzo-2,4,8,10-tetraoxa-3,9-diboraspiro[5.5] undecane. The Pd-deposited BP (Pd/BP) showed highly selective catalytic activity for the hydrogenation of CA to hydrocinnamaldehyde (HCA) under 0.1 MPa of H-2 at 25 degrees C in environmentally preferable solvents such as water and methanol. Of particular note is the recyclability of the hydrogenation catalyst in methanol; repeated 4 h reactions afforded HCA in >90% selectivity with a reaction conversion of 100%. On another front, when the corresponding Au catalyst (Au/BP) was used in the hydrogenation in water, a favorable selective reduction of C=O to cinnamyl alcohol (CAL) (selectivity approximate to 80%) was obtained with 78% reaction conversion under 0.8 MPa of H-2 at 80 degrees C for 12 h. The potential use of BP-supported metal nanoparticles as green catalysts is discussed.
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