4.8 Article

Efficient visible light-mediated cross-dehydrogenative coupling reactions of tertiary amines catalyzed by a polymer-immobilized iridium-based photocatalyst

Journal

GREEN CHEMISTRY
Volume 16, Issue 5, Pages 2438-2442

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4gc00058g

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Funding

  1. Japan Society for the Promotion of Science (JSPS)
  2. Global COE Program (Chemistry Innovation through Cooperation of Science and Engineering)
  3. University of Tokyo
  4. Japan Science and Technology Agency (JST)
  5. Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan

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The immobilization of an iridium-based heterogeneous photocatalyst via a radical polymerization process is described, and its catalytic activity was evaluated for the aerobic phosphonylation reaction of N-aryl tetrahydroisoquinolines under visible light irradiation.

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