4.8 Article

Aerobic oxidation of isosorbide and isomannide employing TEMPO/laccase

Journal

GREEN CHEMISTRY
Volume 16, Issue 4, Pages 2117-2121

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41855c

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Funding

  1. German Federal Ministry of Education and Research (BMBF) [0316044B]
  2. Evonik Industries AG

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The oxidation of the renewable diols isosorbide and isomannide was successfully achieved using a TEMPO/laccase system. Furthermore, various TEMPO-derivatives were tested leading to conversions of up to >99% for the oxidation of isosorbide, isomannide, indanol and a halohydrin to the corresponding ketone.

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